Catalytic activation of C-H and C-C bonds of allylamines via olefin isomerization by transition metal complexes

Chul-Ho Jun, Hyuk Lee, Jae Bum Park, Dae Yon Lee

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

(matrix presented) The metal-catalyzed reaction of olefins with allylamines bearing coordination sites (2-pyridyl groups) was studied. With Ru3(CO)12 as catalyst, activation of C-H bonds led to the formation of ketimines that were hydrolyzed to give asymmetric ketones. With [(C8H14)2RhCl]2, both C-H and C-C bonds were activated and symmetric ketones were formed on hydrolysis. The reaction involves double bond migration of the allylamine to form an aldimine.

Original languageEnglish
Pages (from-to)2161-2164
Number of pages4
JournalOrganic Letters
Volume1
Issue number13
DOIs
Publication statusPublished - 1999 Dec 30

Fingerprint

Allylamine
Coordination Complexes
Alkenes
Isomerization
Ketones
ketones
isomerization
alkenes
Transition metals
Bearings (structural)
Chemical activation
transition metals
activation
Carbon Monoxide
hydrolysis
Hydrolysis
Metals
catalysts
Catalysts
matrices

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Jun, Chul-Ho ; Lee, Hyuk ; Park, Jae Bum ; Lee, Dae Yon. / Catalytic activation of C-H and C-C bonds of allylamines via olefin isomerization by transition metal complexes. In: Organic Letters. 1999 ; Vol. 1, No. 13. pp. 2161-2164.
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Catalytic activation of C-H and C-C bonds of allylamines via olefin isomerization by transition metal complexes. / Jun, Chul-Ho; Lee, Hyuk; Park, Jae Bum; Lee, Dae Yon.

In: Organic Letters, Vol. 1, No. 13, 30.12.1999, p. 2161-2164.

Research output: Contribution to journalArticle

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