Catalytic activation of C-H and C-C bonds of allylamines via olefin isomerization by transition metal complexes

Chul Ho Jun, Hyuk Lee, Jae Bum Park, Dae Yon Lee

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

(matrix presented) The metal-catalyzed reaction of olefins with allylamines bearing coordination sites (2-pyridyl groups) was studied. With Ru3(CO)12 as catalyst, activation of C-H bonds led to the formation of ketimines that were hydrolyzed to give asymmetric ketones. With [(C8H14)2RhCl]2, both C-H and C-C bonds were activated and symmetric ketones were formed on hydrolysis. The reaction involves double bond migration of the allylamine to form an aldimine.

Original languageEnglish
Pages (from-to)2161-2164
Number of pages4
JournalOrganic Letters
Volume1
Issue number13
DOIs
Publication statusPublished - 1999 Dec 30

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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