Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Chul Ho Jun, Dae Yon Lee, Yeon Hee Kim, Hyuk Lee

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

Original languageEnglish
Pages (from-to)2928-2931
Number of pages4
JournalOrganometallics
Volume20
Issue number13
Publication statusPublished - 2001 Jun 25

Fingerprint

Rhodium
rhodium
alcohols
Carbon
Chemical activation
Alcohols
activation
carbon
Alkenes
alkenes
Picolines
Ketones
ketones
Hydrogenation
hydrogenation
Hydrogen
Oxidation
oxidation
Substrates
hydrogen

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Jun, Chul Ho ; Lee, Dae Yon ; Kim, Yeon Hee ; Lee, Hyuk. / Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex. In: Organometallics. 2001 ; Vol. 20, No. 13. pp. 2928-2931.
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Jun, CH, Lee, DY, Kim, YH & Lee, H 2001, 'Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex', Organometallics, vol. 20, no. 13, pp. 2928-2931.

Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex. / Jun, Chul Ho; Lee, Dae Yon; Kim, Yeon Hee; Lee, Hyuk.

In: Organometallics, Vol. 20, No. 13, 25.06.2001, p. 2928-2931.

Research output: Contribution to journalArticle

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