Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Chul-Ho Jun, Dae Yon Lee, Yeon Hee Kim, Hyuk Lee

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K 2 CO 3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

Original languageEnglish
Pages (from-to)2928-2931
Number of pages4
JournalOrganometallics
Volume20
Issue number13
Publication statusPublished - 2001 Jun 25

Fingerprint

Rhodium
rhodium
alcohols
Carbon
Chemical activation
Alcohols
activation
carbon
Alkenes
alkenes
Picolines
Carbon Monoxide
Ketones
ketones
Hydrogenation
hydrogenation
Hydrogen
Oxidation
oxidation
Substrates

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Jun, Chul-Ho ; Lee, Dae Yon ; Kim, Yeon Hee ; Lee, Hyuk. / Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex. In: Organometallics. 2001 ; Vol. 20, No. 13. pp. 2928-2931.
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Jun, C-H, Lee, DY, Kim, YH & Lee, H 2001, 'Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex', Organometallics, vol. 20, no. 13, pp. 2928-2931.

Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex. / Jun, Chul-Ho; Lee, Dae Yon; Kim, Yeon Hee; Lee, Hyuk.

In: Organometallics, Vol. 20, No. 13, 25.06.2001, p. 2928-2931.

Research output: Contribution to journalArticle

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