Catalytic investigation for Fischer-Tropsch synthesis from bio-mass derived syngas

Ki Won Jun; Hyun Seog Roh; Kyong Su Kim; Jae Seong Ryu; Kyu Wan Lee

doi:10.1016/j.apcata.2003.09.034

Catalytic investigation for Fischer-Tropsch synthesis from bio-mass derived syngas

Ki Won Jun, Hyun Seog Roh, Kyong Su Kim, Jae Seong Ryu, Kyu Wan Lee

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

Hydrocarbon synthesis from biomass-derived syngas (bio-syngas) has been investigated as a potential way to use biomass. The Fischer-Tropsch reaction has been carried out using CO/CO₂/H₂/Ar (11/32/52/5 vol.%) mixture as a model for bio-syngas on co-precipitated Fe/Cu/K, Fe/Cu/Si/K and Fe/Cu/Al/K catalysts in a fixed bed reactor. The reaction with the model bio-syngas showed that only CO was converted to hydrocarbons while, in the reaction with a balanced (i.e. H₂-enriched) feed gas, CO₂ was converted to hydrocarbons as well as CO. In the optimization of the catalyst composition that employed bio-syngas, alumina as a structural promoter gave much higher activity for hydrocarbon production than silica. K addition promoted the catalytic activity and the selectivities toward olefins and long-chain hydrocarbons, but too high K promotion caused the gradual deactivation of the catalysts. Some performances of the catalysts that depended on the syngas composition are also presented.

Original language	English
Pages (from-to)	221-226
Number of pages	6
Journal	Applied Catalysis A: General
Volume	259
Issue number	2
DOIs	https://doi.org/10.1016/j.apcata.2003.09.034
Publication status	Published - 2004 Mar 15

Bibliographical note

Funding Information:
The present work was supported by an International Joint Research Grant, No. 99GP2, from New Energy and Industry Technology Development Organization (NEDO), Japan. The authors, especially Kyu-Wan Lee, appreciate it very much.

All Science Journal Classification (ASJC) codes

Catalysis
Process Chemistry and Technology

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@article{d063aad12faf47fab689441821d14f18,

title = "Catalytic investigation for Fischer-Tropsch synthesis from bio-mass derived syngas",

abstract = "Hydrocarbon synthesis from biomass-derived syngas (bio-syngas) has been investigated as a potential way to use biomass. The Fischer-Tropsch reaction has been carried out using CO/CO2/H2/Ar (11/32/52/5 vol.%) mixture as a model for bio-syngas on co-precipitated Fe/Cu/K, Fe/Cu/Si/K and Fe/Cu/Al/K catalysts in a fixed bed reactor. The reaction with the model bio-syngas showed that only CO was converted to hydrocarbons while, in the reaction with a balanced (i.e. H2-enriched) feed gas, CO2 was converted to hydrocarbons as well as CO. In the optimization of the catalyst composition that employed bio-syngas, alumina as a structural promoter gave much higher activity for hydrocarbon production than silica. K addition promoted the catalytic activity and the selectivities toward olefins and long-chain hydrocarbons, but too high K promotion caused the gradual deactivation of the catalysts. Some performances of the catalysts that depended on the syngas composition are also presented.",

author = "Jun, {Ki Won} and Roh, {Hyun Seog} and Kim, {Kyong Su} and Ryu, {Jae Seong} and Lee, {Kyu Wan}",

note = "Funding Information: The present work was supported by an International Joint Research Grant, No. 99GP2, from New Energy and Industry Technology Development Organization (NEDO), Japan. The authors, especially Kyu-Wan Lee, appreciate it very much. ",

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AU - Jun, Ki Won

AU - Roh, Hyun Seog

AU - Kim, Kyong Su

AU - Ryu, Jae Seong

AU - Lee, Kyu Wan

N1 - Funding Information: The present work was supported by an International Joint Research Grant, No. 99GP2, from New Energy and Industry Technology Development Organization (NEDO), Japan. The authors, especially Kyu-Wan Lee, appreciate it very much.

PY - 2004/3/15

Y1 - 2004/3/15

N2 - Hydrocarbon synthesis from biomass-derived syngas (bio-syngas) has been investigated as a potential way to use biomass. The Fischer-Tropsch reaction has been carried out using CO/CO2/H2/Ar (11/32/52/5 vol.%) mixture as a model for bio-syngas on co-precipitated Fe/Cu/K, Fe/Cu/Si/K and Fe/Cu/Al/K catalysts in a fixed bed reactor. The reaction with the model bio-syngas showed that only CO was converted to hydrocarbons while, in the reaction with a balanced (i.e. H2-enriched) feed gas, CO2 was converted to hydrocarbons as well as CO. In the optimization of the catalyst composition that employed bio-syngas, alumina as a structural promoter gave much higher activity for hydrocarbon production than silica. K addition promoted the catalytic activity and the selectivities toward olefins and long-chain hydrocarbons, but too high K promotion caused the gradual deactivation of the catalysts. Some performances of the catalysts that depended on the syngas composition are also presented.

AB - Hydrocarbon synthesis from biomass-derived syngas (bio-syngas) has been investigated as a potential way to use biomass. The Fischer-Tropsch reaction has been carried out using CO/CO2/H2/Ar (11/32/52/5 vol.%) mixture as a model for bio-syngas on co-precipitated Fe/Cu/K, Fe/Cu/Si/K and Fe/Cu/Al/K catalysts in a fixed bed reactor. The reaction with the model bio-syngas showed that only CO was converted to hydrocarbons while, in the reaction with a balanced (i.e. H2-enriched) feed gas, CO2 was converted to hydrocarbons as well as CO. In the optimization of the catalyst composition that employed bio-syngas, alumina as a structural promoter gave much higher activity for hydrocarbon production than silica. K addition promoted the catalytic activity and the selectivities toward olefins and long-chain hydrocarbons, but too high K promotion caused the gradual deactivation of the catalysts. Some performances of the catalysts that depended on the syngas composition are also presented.

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