Catalytic polymerization of anthracene in a recyclable SBA-15 reactor with high iron content by a friedel-crafts alkylation

Jeonghun Kim, Chokkalingam Anand, Siddulu N. Talapaneni, Jungmok You, Salem S. Aldeyab, Eunkyoung Kim, Ajayan Vinu

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Ironing it out: A FeSBA-15 catalyst with a high iron content as well as a large pore diameter has been synthesized and used for the production of soluble poly(methylene anthracene) (PMAn, see scheme). The catalyst is stable, active, reusable, and affords a high yield of high-molecular-weight PMAn. The properties of the PMAns obtained can be controlled by tuning the specific surface area, pore diameter, pore volume, and Fe content of the catalysts.

Original languageEnglish
Pages (from-to)2859-2863
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number12
DOIs
Publication statusPublished - 2012 Mar 19

Fingerprint

Anthracene
Alkylation
Iron
Polymerization
Catalysts
Specific surface area
Tuning
Molecular weight
SBA-15
anthracene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Kim, Jeonghun ; Anand, Chokkalingam ; Talapaneni, Siddulu N. ; You, Jungmok ; Aldeyab, Salem S. ; Kim, Eunkyoung ; Vinu, Ajayan. / Catalytic polymerization of anthracene in a recyclable SBA-15 reactor with high iron content by a friedel-crafts alkylation. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 12. pp. 2859-2863.
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Catalytic polymerization of anthracene in a recyclable SBA-15 reactor with high iron content by a friedel-crafts alkylation. / Kim, Jeonghun; Anand, Chokkalingam; Talapaneni, Siddulu N.; You, Jungmok; Aldeyab, Salem S.; Kim, Eunkyoung; Vinu, Ajayan.

In: Angewandte Chemie - International Edition, Vol. 51, No. 12, 19.03.2012, p. 2859-2863.

Research output: Contribution to journalArticle

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