Cellulose nanofiber composite with bimetallic zeolite imidazole framework for electrochemical supercapacitors

Hemraj M. Yadav, Jong Deok Park, Hyeong Cheol Kang, Jeonghun Kim, Jae Joon Lee

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Cellulose nanofiber (CNF) and hybrid zeolite imidazole framework (HZ) are an emerging biomaterial and a porous carbonous material, respectively. The composite of these two materials could have versatile physiochemical characteristics. A cellulose nanofiber and cobalt-containing zeolite framework-based composite was prepared using an in-situ and eco-friendly chemical method followed by pyrolysis. The composite was comprised of cobalt nanoparticles decorated on highly graphitized N-doped nanoporous carbons (NPC) wrapped with carbon nanotubes (CNTs) produced from the direct carbonization of HZ. By varying the ratio of CNF in the composite, we de-termined the optimal concentration and characterized the derived samples using sophisticated techniques. Scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy (XPS) confirmed the functionalization of CNF in the metallic cobalt-covered N-doped NPC wrapped with CNTs. The CNF–HZNPC composite electrodes show superior electrochemical performance, which is suitable for supercapacitor applications; its specific capacitance is 146 F/g at 1 A/g. Furthermore, the composite electrodes retain a cycling stability of about 90% over charge–discharge cycles at 10 A/g. The superior electrochemical properties of the cellulose make it a promising candidate for developing electrodes for energy storage applications.

Original languageEnglish
Article number395
Pages (from-to)1-10
Number of pages10
JournalNanomaterials
Volume11
Issue number2
DOIs
Publication statusPublished - 2021 Feb

Bibliographical note

Funding Information:
Acknowledgments: This research was supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation, funded by the Ministry of Science, ICT & Future Planning (grant NRF-2016M1A2A2940912 and NRF-2015M1A2A2054996).

Funding Information:
Funding: This research was supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation, funded by the Ministry of Science, ICT & Future Planning (grant NRF-2016M1A2A2940912 and NRF-2015M1A2A2054996). This study was also supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (No. 2020R1C1C1004459).

Publisher Copyright:
© 2021 by the authors. Licensee MDPI, Basel, Switzerland.

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)

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