CH Bond cleavage of 8-quinolinecarbaldehyde by σ,η3-allyl rhodium(III) complexes

Chul Ho Jun, Yeong Gweon Lim

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Formation of σ,η3-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to CH bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted η3-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted η3-allyl rhodium complexes with P(OMe)3 produce β,γ-unsaturated ketones.

Original languageEnglish
Pages (from-to)3357-3360
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number19
DOIs
Publication statusPublished - 1995 May 8

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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