Charge Transport Properties of PEG Substituted Phthalocyanine Polymers

Eunkyoung Kim, Hyo Won Lee

Research output: Contribution to conferencePaper

Abstract

Phthalocyanine polymers substituted with polyethylene glycol (PEG), PPEGPc, were synthesized and characterized by photoelectrochemistry. Thin film of phthalocyanine polymer was coated on a conductive ITO glass using a mixture of soluble PPEGPc in DMF. The PPEGPc film coated ITO electrode showed photocurrent of 3-16 mA/cm3 in a liquid electrolyte system containing hydroquinone. Phthalocyanine polymers substituted with polyethylene glycol showed higher photocurrent generation compared to that with unsubstituted polymer, suggesting that PEG units facilitate transport of generated charge carrier. Solid state PPEGPc photoelectrochemical cell, fabricated by using PPEGPc as charge generation materials and benzidine as a charge transport material, showed photo current of 0.04 ∼ 0.27 mA/cm3 under applied potential of 10V. Photocurrent generation was highly dependent on the PEG chain length, indicating that ethylene oxy groups in PEG participate charge transport. The photocurrent in solid state (ip,s) was correlated to that in liquid cell (ip,l) with a linear relationship of i p,s = 0.025 + 0.015×ip,l. Optimization of photocurrent generation in PPEGPc was attempted by varying the bridging group, PEG chain length, and end group of the polymer.

Original languageEnglish
Pages453-456
Number of pages4
Publication statusPublished - 2000 Dec 1
EventIS and T's NIP16: International Conference on Digital Printing Technologies - Vancouver, BC, Canada
Duration: 2000 Oct 152000 Oct 20

Other

OtherIS and T's NIP16: International Conference on Digital Printing Technologies
CountryCanada
CityVancouver, BC
Period00/10/1500/10/20

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Transport properties
Polyethylene glycols
Charge transfer
Photocurrents
Polymers
Chain length
Photoelectrochemical cells
ITO glass
Liquids
Charge carriers
Ethylene
Electrolytes
Thin films
Electrodes

All Science Journal Classification (ASJC) codes

  • Media Technology
  • Computer Science Applications

Cite this

Kim, E., & Lee, H. W. (2000). Charge Transport Properties of PEG Substituted Phthalocyanine Polymers. 453-456. Paper presented at IS and T's NIP16: International Conference on Digital Printing Technologies, Vancouver, BC, Canada.
Kim, Eunkyoung ; Lee, Hyo Won. / Charge Transport Properties of PEG Substituted Phthalocyanine Polymers. Paper presented at IS and T's NIP16: International Conference on Digital Printing Technologies, Vancouver, BC, Canada.4 p.
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Kim, E & Lee, HW 2000, 'Charge Transport Properties of PEG Substituted Phthalocyanine Polymers' Paper presented at IS and T's NIP16: International Conference on Digital Printing Technologies, Vancouver, BC, Canada, 00/10/15 - 00/10/20, pp. 453-456.

Charge Transport Properties of PEG Substituted Phthalocyanine Polymers. / Kim, Eunkyoung; Lee, Hyo Won.

2000. 453-456 Paper presented at IS and T's NIP16: International Conference on Digital Printing Technologies, Vancouver, BC, Canada.

Research output: Contribution to conferencePaper

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AB - Phthalocyanine polymers substituted with polyethylene glycol (PEG), PPEGPc, were synthesized and characterized by photoelectrochemistry. Thin film of phthalocyanine polymer was coated on a conductive ITO glass using a mixture of soluble PPEGPc in DMF. The PPEGPc film coated ITO electrode showed photocurrent of 3-16 mA/cm3 in a liquid electrolyte system containing hydroquinone. Phthalocyanine polymers substituted with polyethylene glycol showed higher photocurrent generation compared to that with unsubstituted polymer, suggesting that PEG units facilitate transport of generated charge carrier. Solid state PPEGPc photoelectrochemical cell, fabricated by using PPEGPc as charge generation materials and benzidine as a charge transport material, showed photo current of 0.04 ∼ 0.27 mA/cm3 under applied potential of 10V. Photocurrent generation was highly dependent on the PEG chain length, indicating that ethylene oxy groups in PEG participate charge transport. The photocurrent in solid state (ip,s) was correlated to that in liquid cell (ip,l) with a linear relationship of i p,s = 0.025 + 0.015×ip,l. Optimization of photocurrent generation in PPEGPc was attempted by varying the bridging group, PEG chain length, and end group of the polymer.

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Kim E, Lee HW. Charge Transport Properties of PEG Substituted Phthalocyanine Polymers. 2000. Paper presented at IS and T's NIP16: International Conference on Digital Printing Technologies, Vancouver, BC, Canada.