Abstract
The transient yellow color observed inthe cycloaddition of homobenzvalene (HB) with tetracyanoethylen (TCNE) is associated with the charge‐transfer complex [HB, TCNE]. The deliberate photoexcitation of [HB, TCNE] affords a mixture of charge‐transfer cycloadducts (1, 2, 3) that differs from that obtained in thermal cycloaddition. The relationship of [hb + TCNE.] radical‐io pai (as the critical reactive intermediate in charge‐transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 1209-1218 |
| Number of pages | 10 |
| Journal | Chemische Berichte |
| Volume | 123 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1990 Jan 1 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
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Charge‐Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene. / Kim, Eunkyoung; Kochi, Jay K.; Christl, Manfred.
In: Chemische Berichte, Vol. 123, No. 5, 01.01.1990, p. 1209-1218.Research output: Contribution to journal › Article
TY - JOUR
T1 - Charge‐Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene
AU - Kim, Eunkyoung
AU - Kochi, Jay K.
AU - Christl, Manfred
PY - 1990/1/1
Y1 - 1990/1/1
N2 - The transient yellow color observed inthe cycloaddition of homobenzvalene (HB) with tetracyanoethylen (TCNE) is associated with the charge‐transfer complex [HB, TCNE]. The deliberate photoexcitation of [HB, TCNE] affords a mixture of charge‐transfer cycloadducts (1, 2, 3) that differs from that obtained in thermal cycloaddition. The relationship of [hb + TCNE.] radical‐io pai (as the critical reactive intermediate in charge‐transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.
AB - The transient yellow color observed inthe cycloaddition of homobenzvalene (HB) with tetracyanoethylen (TCNE) is associated with the charge‐transfer complex [HB, TCNE]. The deliberate photoexcitation of [HB, TCNE] affords a mixture of charge‐transfer cycloadducts (1, 2, 3) that differs from that obtained in thermal cycloaddition. The relationship of [hb + TCNE.] radical‐io pai (as the critical reactive intermediate in charge‐transfer cycloaddition) to the activation process for thermal cycloaddition is discussed.
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U2 - 10.1002/cber.19901230538
DO - 10.1002/cber.19901230538
M3 - Article
VL - 123
SP - 1209
EP - 1218
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 5
ER -