Chelation-accelerated sequential decarbonylation of formate and alkoxycarbonylation of aryl halides using a combined Ru and Pd catalyst

Sangwon Ko, Chongmok Lee, Moon Gun Choi, Youngim Na, Sukbok Chang

Research output: Contribution to journalArticle

100 Citations (Scopus)

Abstract

An efficient cooperative catalyst system for the coupling of a wide range of organic electrophiles with chelated formate is reported to afford aryl and alkenyl esters by the simultaneous employment of Ru and Pd catalyst, in which ruthenium first promotes chelation-accelerated decarbonylation of formate to release CO and carbinol that are presumed to be transferred, still chelated to Ru, into Pd catalyst, which catalyzes alkoxycarbonylation of the organic electrophiles.

Original languageEnglish
Pages (from-to)1607-1610
Number of pages4
JournalJournal of Organic Chemistry
Volume68
Issue number4
DOIs
Publication statusPublished - 2003 Feb 21

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formic acid
Chelation
Catalysts
Ruthenium
Carbon Monoxide
Methanol
Esters

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Ko, Sangwon ; Lee, Chongmok ; Choi, Moon Gun ; Na, Youngim ; Chang, Sukbok. / Chelation-accelerated sequential decarbonylation of formate and alkoxycarbonylation of aryl halides using a combined Ru and Pd catalyst. In: Journal of Organic Chemistry. 2003 ; Vol. 68, No. 4. pp. 1607-1610.
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Chelation-accelerated sequential decarbonylation of formate and alkoxycarbonylation of aryl halides using a combined Ru and Pd catalyst. / Ko, Sangwon; Lee, Chongmok; Choi, Moon Gun; Na, Youngim; Chang, Sukbok.

In: Journal of Organic Chemistry, Vol. 68, No. 4, 21.02.2003, p. 1607-1610.

Research output: Contribution to journalArticle

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AU - Chang, Sukbok

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