Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts

Chul Ho Jun; Choong Woon Moon; Dae Yon Lee

doi:10.1002/1521-3765(20020603)8:11<2422::AID-CHEM2422>3.0.CO;2-B

Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts

Chul Ho Jun, Choong Woon Moon, Dae Yon Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

155 Citations (Scopus)

Abstract

Herein we describe the chelation-assisted C-H and C-C bond activation of carbonyl compounds by Rh^I catalysts. Hydroacylation of olefins was accomplished by utilizing 2-amino-3-picoline as a chelation auxiliary. The same strategy was employed for the C-C bond activation of unstrained ketones. Allylamine 24 was devised as a synthon of formaldehyde. Hydroiminoacylation of alkynes with allylamine 24 was applied to the alkyne cleavage by the aid of cyclohexylamine.

Original language	English
Pages (from-to)	2422-2428
Number of pages	7
Journal	Chemistry - A European Journal
Volume	8
Issue number	11
DOIs	https://doi.org/10.1002/1521-3765(20020603)8:11<2422::AID-CHEM2422>3.0.CO;2-B
Publication status	Published - 2002 Jun 3

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/1521-3765(20020603)8:11<2422::AID-CHEM2422>3.0.CO;2-B

Cite this

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abstract = "Herein we describe the chelation-assisted C-H and C-C bond activation of carbonyl compounds by RhI catalysts. Hydroacylation of olefins was accomplished by utilizing 2-amino-3-picoline as a chelation auxiliary. The same strategy was employed for the C-C bond activation of unstrained ketones. Allylamine 24 was devised as a synthon of formaldehyde. Hydroiminoacylation of alkynes with allylamine 24 was applied to the alkyne cleavage by the aid of cyclohexylamine.",

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year = "2002",

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Y1 - 2002/6/3

N2 - Herein we describe the chelation-assisted C-H and C-C bond activation of carbonyl compounds by RhI catalysts. Hydroacylation of olefins was accomplished by utilizing 2-amino-3-picoline as a chelation auxiliary. The same strategy was employed for the C-C bond activation of unstrained ketones. Allylamine 24 was devised as a synthon of formaldehyde. Hydroiminoacylation of alkynes with allylamine 24 was applied to the alkyne cleavage by the aid of cyclohexylamine.

AB - Herein we describe the chelation-assisted C-H and C-C bond activation of carbonyl compounds by RhI catalysts. Hydroacylation of olefins was accomplished by utilizing 2-amino-3-picoline as a chelation auxiliary. The same strategy was employed for the C-C bond activation of unstrained ketones. Allylamine 24 was devised as a synthon of formaldehyde. Hydroiminoacylation of alkynes with allylamine 24 was applied to the alkyne cleavage by the aid of cyclohexylamine.

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Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts

Abstract

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