Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts

Chul Ho Jun, Choong Woon Moon, Dae Yon Lee

Research output: Contribution to journalArticle

146 Citations (Scopus)

Abstract

Herein we describe the chelation-assisted C-H and C-C bond activation of carbonyl compounds by RhI catalysts. Hydroacylation of olefins was accomplished by utilizing 2-amino-3-picoline as a chelation auxiliary. The same strategy was employed for the C-C bond activation of unstrained ketones. Allylamine 24 was devised as a synthon of formaldehyde. Hydroiminoacylation of alkynes with allylamine 24 was applied to the alkyne cleavage by the aid of cyclohexylamine.

Original languageEnglish
Pages (from-to)2422-2428
Number of pages7
JournalChemistry - A European Journal
Volume8
Issue number11
DOIs
Publication statusPublished - 2002 Jun 3

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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