Chelation-assisted hydrative dimerization of 1-alkyne forming α,β-enones by an Rh(I) catalyst

Jun Park Young, Bong Il Kwon, Jeong Ae Ahn, Hyuk Lee, Chul Ho Jun

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The intermolecular hydrative dimerization of 1-alkyne was developed through the chelation-assisted catalytic system with Rh(I)/2-amino-3-picoline. This novel transformation afforded branched and linear α,β-enones directly from two 1-alkyne molecules and H2O. The results demonstrate that a branch/linear ratio can be controlled by the alkyl substituent of 1-alkyne.

Original languageEnglish
Pages (from-to)13892-13893
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number43
DOIs
Publication statusPublished - 2004 Nov 3

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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