Chelation-assisted hydroacylation

Chul Ho Jun, Jun Bae Hong, Dae Yon Lee

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

The C-H bond of aldehyde can be cleaved by a transition metal complex to give acylmetal hydride. If subsequent decarbonylation is suppressed, hydroacylation of olefin can proceed. Cyclometalation is one of the promising ways to suppress decarbonylation. In this account, some of the work on chelation-assisted hydroacylation is reviewed. The mechanistic studies are presented as stoichiometric hydroacylation. Catalytic reactions with various substrates are also discussed.

Original languageEnglish
Pages (from-to)1-12
Number of pages12
JournalSynlett
Issue number1
DOIs
Publication statusPublished - 1999 Jan 1

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All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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