Chemical bonding character and physicochemical properties of mesoporous zinc oxide-layered titanate nanocomposites

Tae Woo Kim, Seong Ju Hwang, Yiseul Park, Wonyong Choi, Jin Ho Choy

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

We have investigated the chemical bonding character and physicochemical properties of mesoporous zinc oxide-layered titanate nanocomposites synthesized by an exfoliation-restacking route. According to our analyses using X-ray diffraction, high resolution transmission electron microscopy, and N2 adsorption-desorption isotherm measurements, nanocrystalline zinc oxides are stabilized not only in the interlayer space of the host titanate but also in the mesopores of the nanocomposites formed by the house-of-card type stacking of the crystallites. X-ray absorption spectroscopic analyses at Ti K- and Zn K-edges clearly demonstrate that nanocrystalline zinc oxides crystallized with a Wurzite type structure, and the lepidocrocite structure of the host titanate remains unchanged after hybridization and postcalcination. Upon hybridization with zinc oxide nanoparticles, the photocatalytic activity of layered titanate is enhanced with respect to the oxidative photodegradation of phenol and dichloroacetate. But of greater importance is that the chemical stability of guest zinc oxide against acidic corrosion is greatly improved by hybridization with layered titanate. In this regard, the present hybridization technique enables the application of chemically unstable nanostructured zinc oxides even in corrosive environments.

Original languageEnglish
Pages (from-to)1658-1664
Number of pages7
JournalJournal of Physical Chemistry C
Volume111
Issue number4
DOIs
Publication statusPublished - 2007 Feb 1

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Zinc Oxide
Zinc oxide
zinc oxides
Nanocomposites
nanocomposites
Caustics
Chemical stability
Photodegradation
X ray absorption
cards
High resolution transmission electron microscopy
Phenol
Crystallites
phenols
crystallites
Phenols
Isotherms
interlayers
Desorption
corrosion

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

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abstract = "We have investigated the chemical bonding character and physicochemical properties of mesoporous zinc oxide-layered titanate nanocomposites synthesized by an exfoliation-restacking route. According to our analyses using X-ray diffraction, high resolution transmission electron microscopy, and N2 adsorption-desorption isotherm measurements, nanocrystalline zinc oxides are stabilized not only in the interlayer space of the host titanate but also in the mesopores of the nanocomposites formed by the house-of-card type stacking of the crystallites. X-ray absorption spectroscopic analyses at Ti K- and Zn K-edges clearly demonstrate that nanocrystalline zinc oxides crystallized with a Wurzite type structure, and the lepidocrocite structure of the host titanate remains unchanged after hybridization and postcalcination. Upon hybridization with zinc oxide nanoparticles, the photocatalytic activity of layered titanate is enhanced with respect to the oxidative photodegradation of phenol and dichloroacetate. But of greater importance is that the chemical stability of guest zinc oxide against acidic corrosion is greatly improved by hybridization with layered titanate. In this regard, the present hybridization technique enables the application of chemically unstable nanostructured zinc oxides even in corrosive environments.",
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Chemical bonding character and physicochemical properties of mesoporous zinc oxide-layered titanate nanocomposites. / Kim, Tae Woo; Hwang, Seong Ju; Park, Yiseul; Choi, Wonyong; Choy, Jin Ho.

In: Journal of Physical Chemistry C, Vol. 111, No. 4, 01.02.2007, p. 1658-1664.

Research output: Contribution to journalArticle

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