The occurrence of synthetic and natural hormones in an aqueous environment poses significant risks to humans because of their endocrine-disrupting activity. Autonomous self-propelled and remotely actuated nano/microrobots have emerged as a new field that encompasses a wide range of potential applications, including sensing, detection and elimination/degradation of emerging pollutants. In this work, we develop programmable polypyrrole-based (PPy, outer functional layer) microrobots incorporated with a Pt catalytic layer and paramagnetic iron nanoparticles (Fe3O4) to provide self-propulsion and a magnetic response for the highly efficient removal of oestrogenic pollutants. As the pH of the tested water alters, the surface charge of PPy/Fe3O4/Pt microrobots gradually changes, leading to affinity modulation. As microrobots move inside the solution, they collect oestrogen fibres and subsequently weave macroscopic webs on the surface. Our results suggest that motion-controllable microrobots with adjustable surface chemistry could provide a suitable platform for the highly efficient removal of hormonal pollutants.
Bibliographical noteFunding Information:
M.P. was supported by the Ministry of Education, Youth and Sports (Czech Republic) grant no. LL2002 under the ERC CZ programme. B.K. was supported by the Czech Science Foundation (GACR no. 20-20201S).
All Science Journal Classification (ASJC) codes
- Artificial Intelligence
- Computer Vision and Pattern Recognition
- Computer Networks and Communications
- Human-Computer Interaction