Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

Zheng Guo Lin, Lin Yuan Fan, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Bao Kuan Chen, Ali Haider, Bo Wang, Ulrich Kortz, Chang Wen Hu

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Abstract

The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

Original languageEnglish
Pages (from-to)7811-7813
Number of pages3
JournalInorganic Chemistry
Volume55
Issue number16
DOIs
Publication statusPublished - 2016 Aug 15

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Lin, Z. G., Fan, L. Y., Kondinski, A., Vankova, N., Heine, T., Chen, B. K., Haider, A., Wang, B., Kortz, U., & Hu, C. W. (2016). Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations. Inorganic Chemistry, 55(16), 7811-7813. https://doi.org/10.1021/acs.inorgchem.6b01005