Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

Zheng Guo Lin; Lin Yuan Fan; Aleksandar Kondinski; Nina Vankova; Thomas Heine; Bao Kuan Chen; Ali Haider; Bo Wang; Ulrich Kortz; Chang Wen Hu

doi:10.1021/acs.inorgchem.6b01005

Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

Zheng Guo Lin, Lin Yuan Fan, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Bao Kuan Chen, Ali Haider, Bo Wang, Ulrich Kortz, Chang Wen Hu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The chiral dodecanuclear palladium(II) thio cluster LaPd₁₂(C₃H₅NO₂S)₃(C₃H₆NO₂S)₂₁ (1) was prepared by reacting l-cysteine (l-Cys) with PdCl₂ and La₂O₃ in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, ¹³C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

Original language	English
Pages (from-to)	7811-7813
Number of pages	3
Journal	Inorganic Chemistry
Volume	55
Issue number	16
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01005
Publication status	Published - 2016 Aug 15

Bibliographical note

Funding Information:
This work was supported by the National Natural Science Foundation of China (Grants 21173021, 21231002, 21276026, and 21401111) and the 973 Program (Grant 2014CB932103). U.K. acknowledges the German Science Foundation (Grant KO- 2288/20-1) and Jacobs University

Publisher Copyright:
© 2016 American Chemical Society.

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.6b01005

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title = "Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations",

abstract = "The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.",

author = "Lin, {Zheng Guo} and Fan, {Lin Yuan} and Aleksandar Kondinski and Nina Vankova and Thomas Heine and Chen, {Bao Kuan} and Ali Haider and Bo Wang and Ulrich Kortz and Hu, {Chang Wen}",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (Grants 21173021, 21231002, 21276026, and 21401111) and the 973 Program (Grant 2014CB932103). U.K. acknowledges the German Science Foundation (Grant KO- 2288/20-1) and Jacobs University Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = aug,

day = "15",

doi = "10.1021/acs.inorgchem.6b01005",

language = "English",

volume = "55",

pages = "7811--7813",

journal = "Inorganic Chemistry",

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Chiral Dodecanuclear Palladium(II) Thio Cluster : Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations. / Lin, Zheng Guo; Fan, Lin Yuan; Kondinski, Aleksandar; Vankova, Nina; Heine, Thomas; Chen, Bao Kuan; Haider, Ali; Wang, Bo; Kortz, Ulrich; Hu, Chang Wen.

In: Inorganic Chemistry, Vol. 55, No. 16, 15.08.2016, p. 7811-7813.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

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T2 - Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

AU - Lin, Zheng Guo

AU - Fan, Lin Yuan

AU - Kondinski, Aleksandar

AU - Vankova, Nina

AU - Heine, Thomas

AU - Chen, Bao Kuan

AU - Haider, Ali

AU - Wang, Bo

AU - Kortz, Ulrich

AU - Hu, Chang Wen

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (Grants 21173021, 21231002, 21276026, and 21401111) and the 973 Program (Grant 2014CB932103). U.K. acknowledges the German Science Foundation (Grant KO- 2288/20-1) and Jacobs University Publisher Copyright: © 2016 American Chemical Society.

PY - 2016/8/15

Y1 - 2016/8/15

N2 - The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

AB - The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

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Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

Abstract

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