Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

Research output: Contribution to journalArticle

Abstract

A boronic acid moiety can bind to nucleophilic species, such as fluoride ions and 1,2-diols, and arylboronates are converted to the corresponding phenols by treatment with hydrogen peroxide. Based on these reactivity profiles of boron compounds, a variety of boronic acid and boronate-based fluorescent chemosensors have been developed for detecting biologically relevant species. This feature article highlights recent advances that have been made in the development of chemosensors of these types for monitoring carbohydrates, dopamine, fluorides, metal ions and hydrogen peroxide. © 2012 The Royal Society of Chemistry.
Original languageEnglish
Pages (from-to)5956-5967
Number of pages2
JournalChemical Communications
Volume48
Issue number48
Publication statusPublished - 2012 May 21

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Boronic Acids
Cobalt
Fluorides
Hydrogen peroxide
Hydrogen Peroxide
Boron Compounds
Boron compounds
Acids
Phenols
Carbohydrates
Metal ions
Dopamine
Ions
Monitoring

Cite this

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title = "Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes",
abstract = "A boronic acid moiety can bind to nucleophilic species, such as fluoride ions and 1,2-diols, and arylboronates are converted to the corresponding phenols by treatment with hydrogen peroxide. Based on these reactivity profiles of boron compounds, a variety of boronic acid and boronate-based fluorescent chemosensors have been developed for detecting biologically relevant species. This feature article highlights recent advances that have been made in the development of chemosensors of these types for monitoring carbohydrates, dopamine, fluorides, metal ions and hydrogen peroxide. {\circledC} 2012 The Royal Society of Chemistry.",
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Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes. / Shin, Injae.

In: Chemical Communications, Vol. 48, No. 48, 21.05.2012, p. 5956-5967.

Research output: Contribution to journalArticle

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AU - Shin, Injae

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AB - A boronic acid moiety can bind to nucleophilic species, such as fluoride ions and 1,2-diols, and arylboronates are converted to the corresponding phenols by treatment with hydrogen peroxide. Based on these reactivity profiles of boron compounds, a variety of boronic acid and boronate-based fluorescent chemosensors have been developed for detecting biologically relevant species. This feature article highlights recent advances that have been made in the development of chemosensors of these types for monitoring carbohydrates, dopamine, fluorides, metal ions and hydrogen peroxide. © 2012 The Royal Society of Chemistry.

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