Cobalt(III) complex of ethylenediamine-N,N′-bis-α-(β-phenyl)-propionic acid

Moo jin Jun, Jinwood Cheon

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A novel optically active ONNO-type tetradentate ligand, ethylenediamine-N,N′-bis-α-(β-phenyl)-propionic acid (edbp), and its cobalt(III) complex have been synthesized via the PbO2 oxidation method. During the preparation of diaqua cobalt(III) complexes of edbp, [Co(edbp)(H2O)2]+, the ligand has coordinated specifically to the cobalt(III) ion to give only one isomer, cis-α, which has been characterized by electronic absorption, 1H NMR and IR spectra, and elemental analysis. It is of interest that this is one of the few CoIII (edda)X2 type complex preparations, which gives only one isomer with stereospecificity.

Original languageEnglish
Pages (from-to)63-67
Number of pages5
JournalPolyhedron
Volume13
Issue number1
DOIs
Publication statusPublished - 1994

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Cobalt(III) complex of ethylenediamine-N,N′-bis-α-(β-phenyl)-propionic acid'. Together they form a unique fingerprint.

Cite this