Combined H 2O and CO 2 reforming of CH 4 over Ce-promoted Ni/Al 2O 3 catalyst for gas to liquid (GTL) process: Enhancement of Ni-CeO 2 interaction

Kee Young Koo, Hyun Seog Roh, Un Ho Jung, Wang Lai Yoon

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The effect of Ni-Ce loading method on the catalytic activity and coke formation over Ce-promoted Ni/Al 2O 3 catalysts was investigated in combined steam and carbon dioxide reforming of methane (CSCRM) to produce synthesis gas with a H 2/CO ratio of 2 for gas to liquid (GTL) process. 12 wt%Ni-6 wt%Ce/Al 2O 3 catalysts prepared by a co-impregnation method exhibited higher catalytic performance and less coke formation than 12 wt%Ni/6 wt%Ce/Al 2O 3 and 6 wt%Ce/12 wt%Ni/Al 2O 3 catalysts prepared by a sequential impregnation method due to the improvement of Ni dispersion and high oxygen storage capacity resulting from the intimate contact between Ni and CeO 2 on the surface of the catalyst.

Original languageEnglish
Pages (from-to)126-130
Number of pages5
JournalCatalysis Today
Volume185
Issue number1
DOIs
Publication statusPublished - 2012 May 20

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Carbon Monoxide
Reforming reactions
Gases
Catalysts
Liquids
Impregnation
Coke
Synthesis gas
Methane
Steam
Carbon Dioxide
Catalyst activity
Carbon dioxide
Oxygen

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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abstract = "The effect of Ni-Ce loading method on the catalytic activity and coke formation over Ce-promoted Ni/Al 2O 3 catalysts was investigated in combined steam and carbon dioxide reforming of methane (CSCRM) to produce synthesis gas with a H 2/CO ratio of 2 for gas to liquid (GTL) process. 12 wt{\%}Ni-6 wt{\%}Ce/Al 2O 3 catalysts prepared by a co-impregnation method exhibited higher catalytic performance and less coke formation than 12 wt{\%}Ni/6 wt{\%}Ce/Al 2O 3 and 6 wt{\%}Ce/12 wt{\%}Ni/Al 2O 3 catalysts prepared by a sequential impregnation method due to the improvement of Ni dispersion and high oxygen storage capacity resulting from the intimate contact between Ni and CeO 2 on the surface of the catalyst.",
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Combined H 2O and CO 2 reforming of CH 4 over Ce-promoted Ni/Al 2O 3 catalyst for gas to liquid (GTL) process : Enhancement of Ni-CeO 2 interaction. / Koo, Kee Young; Roh, Hyun Seog; Jung, Un Ho; Yoon, Wang Lai.

In: Catalysis Today, Vol. 185, No. 1, 20.05.2012, p. 126-130.

Research output: Contribution to journalArticle

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