Combined H2O and CO2 reforming of CH4 over nano-sized Ni/MgO-Al2O3 catalysts for synthesis gas production for gas to liquid (GTL): Effect of Mg/Al mixed ratio on coke formation

Kee Young Koo, Hyunseog Roh, Un Ho Jung, Dong Joo Seo, Yong Seog Seo, Wang Lai Yoon

Research output: Contribution to journalArticle

61 Citations (Scopus)

Abstract

Nano-sized Ni catalysts were prepared by using MgO-Al2O3 mixed oxides from hydrotalcite-like structure as a support. The property of support was controlled with various Mg/Al mixed ratio to enhance coke resistance in combined H2O and CO2 reforming of CH4 (CSCRM) to produce synthesis gas (H2/CO = 2) for gas to liquid (GTL). 12% Ni/MgO-Al2O3 catalyst with Mg/Al of 0.5 shows the highest activity in CSCRM due to high coke resistance, resulting from nano-sized Ni particles strongly interacting with the support.

Original languageEnglish
Pages (from-to)166-171
Number of pages6
JournalCatalysis Today
Volume146
Issue number1-2
DOIs
Publication statusPublished - 2009 Aug 15

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hydrotalcite
Synthesis gas
Reforming reactions
Coke
Gases
Catalysts
Liquids
Carbon Monoxide
Oxides

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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title = "Combined H2O and CO2 reforming of CH4 over nano-sized Ni/MgO-Al2O3 catalysts for synthesis gas production for gas to liquid (GTL): Effect of Mg/Al mixed ratio on coke formation",
abstract = "Nano-sized Ni catalysts were prepared by using MgO-Al2O3 mixed oxides from hydrotalcite-like structure as a support. The property of support was controlled with various Mg/Al mixed ratio to enhance coke resistance in combined H2O and CO2 reforming of CH4 (CSCRM) to produce synthesis gas (H2/CO = 2) for gas to liquid (GTL). 12{\%} Ni/MgO-Al2O3 catalyst with Mg/Al of 0.5 shows the highest activity in CSCRM due to high coke resistance, resulting from nano-sized Ni particles strongly interacting with the support.",
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Combined H2O and CO2 reforming of CH4 over nano-sized Ni/MgO-Al2O3 catalysts for synthesis gas production for gas to liquid (GTL) : Effect of Mg/Al mixed ratio on coke formation. / Koo, Kee Young; Roh, Hyunseog; Jung, Un Ho; Seo, Dong Joo; Seo, Yong Seog; Yoon, Wang Lai.

In: Catalysis Today, Vol. 146, No. 1-2, 15.08.2009, p. 166-171.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Combined H2O and CO2 reforming of CH4 over nano-sized Ni/MgO-Al2O3 catalysts for synthesis gas production for gas to liquid (GTL)

T2 - Effect of Mg/Al mixed ratio on coke formation

AU - Koo, Kee Young

AU - Roh, Hyunseog

AU - Jung, Un Ho

AU - Seo, Dong Joo

AU - Seo, Yong Seog

AU - Yoon, Wang Lai

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