Comparative study on nano-sized 1 wt% Pt/Ce 0.8Zr 0.2O 2 and 1 wt% Pt/Ce 0.2Zr 0.8O 2 catalysts for a single stage water gas shift reaction

Dae Woon Jeong, Hari S. Potdar, Hyunseog Roh

Research output: Contribution to journalArticle

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Abstract

A comparative study on nano-sized Pt/Ce 0.8 Zr 0.2O 2 and Pt/Ce 0.2Zr 0.8O 2 catalysts in a single stage water gas shift (WGS) reaction was carried out. These catalysts were prepared by impregnating 1 wt% Pt on nano-sized cubic (Ce 0.8 Zr 0.2O 2) and tetragonal (Ce 0.2Zr 0.8O 2) supports. Both catalysts have been applied to WGS under identical conditions to understand beneficial effect of cubic/tetragonal phases of Ce(1 - x)Zr (x)O 2. 1 wt% Pt/Ce 0.8 Zr 0.2O 2 exhibited higher CO conversion than 1 wt% Pt/Ce 0.2Zr 0.8O 2. In addition, 1 wt%Pt/Ce 0.8 Zr 0.2O 2 catalyst showed relatively stable activity with time on stream. The high activity/stability of 1 wt% Pt/Ce 0.8 Zr 0.2O 2 catalyst was correlated to its higher Pt dispersion and easier reducibility.

Original languageEnglish
Pages (from-to)439-444
Number of pages6
JournalCatalysis Letters
Volume142
Issue number4
DOIs
Publication statusPublished - 2012 Apr 1

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Water gas shift
Catalysts
Carbon Monoxide
Catalyst supports

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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title = "Comparative study on nano-sized 1 wt{\%} Pt/Ce 0.8Zr 0.2O 2 and 1 wt{\%} Pt/Ce 0.2Zr 0.8O 2 catalysts for a single stage water gas shift reaction",
abstract = "A comparative study on nano-sized Pt/Ce 0.8 Zr 0.2O 2 and Pt/Ce 0.2Zr 0.8O 2 catalysts in a single stage water gas shift (WGS) reaction was carried out. These catalysts were prepared by impregnating 1 wt{\%} Pt on nano-sized cubic (Ce 0.8 Zr 0.2O 2) and tetragonal (Ce 0.2Zr 0.8O 2) supports. Both catalysts have been applied to WGS under identical conditions to understand beneficial effect of cubic/tetragonal phases of Ce(1 - x)Zr (x)O 2. 1 wt{\%} Pt/Ce 0.8 Zr 0.2O 2 exhibited higher CO conversion than 1 wt{\%} Pt/Ce 0.2Zr 0.8O 2. In addition, 1 wt{\%}Pt/Ce 0.8 Zr 0.2O 2 catalyst showed relatively stable activity with time on stream. The high activity/stability of 1 wt{\%} Pt/Ce 0.8 Zr 0.2O 2 catalyst was correlated to its higher Pt dispersion and easier reducibility.",
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Comparative study on nano-sized 1 wt% Pt/Ce 0.8Zr 0.2O 2 and 1 wt% Pt/Ce 0.2Zr 0.8O 2 catalysts for a single stage water gas shift reaction. / Jeong, Dae Woon; Potdar, Hari S.; Roh, Hyunseog.

In: Catalysis Letters, Vol. 142, No. 4, 01.04.2012, p. 439-444.

Research output: Contribution to journalArticle

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N2 - A comparative study on nano-sized Pt/Ce 0.8 Zr 0.2O 2 and Pt/Ce 0.2Zr 0.8O 2 catalysts in a single stage water gas shift (WGS) reaction was carried out. These catalysts were prepared by impregnating 1 wt% Pt on nano-sized cubic (Ce 0.8 Zr 0.2O 2) and tetragonal (Ce 0.2Zr 0.8O 2) supports. Both catalysts have been applied to WGS under identical conditions to understand beneficial effect of cubic/tetragonal phases of Ce(1 - x)Zr (x)O 2. 1 wt% Pt/Ce 0.8 Zr 0.2O 2 exhibited higher CO conversion than 1 wt% Pt/Ce 0.2Zr 0.8O 2. In addition, 1 wt%Pt/Ce 0.8 Zr 0.2O 2 catalyst showed relatively stable activity with time on stream. The high activity/stability of 1 wt% Pt/Ce 0.8 Zr 0.2O 2 catalyst was correlated to its higher Pt dispersion and easier reducibility.

AB - A comparative study on nano-sized Pt/Ce 0.8 Zr 0.2O 2 and Pt/Ce 0.2Zr 0.8O 2 catalysts in a single stage water gas shift (WGS) reaction was carried out. These catalysts were prepared by impregnating 1 wt% Pt on nano-sized cubic (Ce 0.8 Zr 0.2O 2) and tetragonal (Ce 0.2Zr 0.8O 2) supports. Both catalysts have been applied to WGS under identical conditions to understand beneficial effect of cubic/tetragonal phases of Ce(1 - x)Zr (x)O 2. 1 wt% Pt/Ce 0.8 Zr 0.2O 2 exhibited higher CO conversion than 1 wt% Pt/Ce 0.2Zr 0.8O 2. In addition, 1 wt%Pt/Ce 0.8 Zr 0.2O 2 catalyst showed relatively stable activity with time on stream. The high activity/stability of 1 wt% Pt/Ce 0.8 Zr 0.2O 2 catalyst was correlated to its higher Pt dispersion and easier reducibility.

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