Complex organic molecules are released during thermal reduction of graphite oxides

Zdeněk Sofer, Petr Šimek, Martin Pumera

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Thermal exfoliation and deoxygenation of graphite oxide is one of the major routes for the preparation of large quantities of graphene-based materials. It is commonly believed that thermal exfoliation leads to the release of H 2O, CO and CO2 gases. Here we show for the first time that in addition to these small simple molecules, there is a wide variety of complex organic molecules that are released from graphite oxide during the exfoliation process, such as alkanes, substituted polycyclic aromatic hydrocarbons and heterocyclic molecules. The compositions of the released volatile compounds depend on the exfoliation atmosphere (Ar, H2), pressure and the preparation methods of graphite oxide (such as Hofmann, Staudenmaier or Hummers). The structures of the decomposition products reflect the characters of graphite oxide precursors and are also directly related to the defects in the graphene products. As such, these findings have profound influences on our understanding on the structural defects of reduced graphenes, which consequently provide further insights into their properties.

Original languageEnglish
Pages (from-to)9257-9264
Number of pages8
JournalPhysical Chemistry Chemical Physics
Volume15
Issue number23
DOIs
Publication statusPublished - 2013 Jun 21

Fingerprint

Graphite
Oxides
graphite
Molecules
oxides
molecules
graphene
deoxygenation
preparation
defects
polycyclic aromatic hydrocarbons
products
alkanes
Defects
Alkanes
Polycyclic Aromatic Hydrocarbons
routes
Carbon Monoxide
decomposition
atmospheres

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

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Complex organic molecules are released during thermal reduction of graphite oxides. / Sofer, Zdeněk; Šimek, Petr; Pumera, Martin.

In: Physical Chemistry Chemical Physics, Vol. 15, No. 23, 21.06.2013, p. 9257-9264.

Research output: Contribution to journalArticle

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