Comprehensive adsorption characteristics of a newly synthesized and sustainable anti-corrosion catalyst on mild steel surface exposed to a highly corrosive electrolytic solution

Raman Kumar, Hansung Kim, Reddicherla Umapathi, Ompal Singh Yadav, Gurmeet Singh

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new environmental-friendly imine compound viz. 4-(2-amino-3-methylphenyl)imino)methyl)benzaldehyde (AMIB) was sustainably synthesized at room temperature utilizing green solvents, reagents and assessed as an anti-corrosion catalyst for the commercially important mild steel (MS) alloy subjected to highly aggressive 0.5 M sulphuric acid (H 2 SO 4 ) solution by several electrochemical methods (polarization techniques and Electrochemical impedance spectroscopy) allied with various surface characterization techniques such as attenuated total reflectance (ATR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and atomic force microscopy (AFM). Furthermore, the experimental results were theoretically supplemented by density functional theory (DFT) treatment. AMIB delivered significant corrosion protection even at very low concentrations and at various temperatures. The findings from electrochemical and surface characterization techniques were also supplemented by temperature kinetics study. The adsorption mechanism of AMIB molecules on metal substrate follow Langmuir's adsorption isotherm. The overall corrosion mitigation mechanism assessed from various techniques and methods was found to be comprehensive in nature. The present study may pave the way for combating corrosion with this cost effective and eco-friendly strategy.

Original languageEnglish
Pages (from-to)37-48
Number of pages12
JournalJournal of Molecular Liquids
Volume268
DOIs
Publication statusPublished - 2018 Oct 15

Fingerprint

Caustics
Carbon steel
corrosion
steels
Corrosion
Adsorption
catalysts
Catalysts
adsorption
Imines
Corrosion protection
Alloy steel
Electrochemical impedance spectroscopy
Adsorption isotherms
Temperature
Density functional theory
Energy dispersive spectroscopy
Atomic force microscopy
Metals
Polarization

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "Comprehensive adsorption characteristics of a newly synthesized and sustainable anti-corrosion catalyst on mild steel surface exposed to a highly corrosive electrolytic solution",
abstract = "A new environmental-friendly imine compound viz. 4-(2-amino-3-methylphenyl)imino)methyl)benzaldehyde (AMIB) was sustainably synthesized at room temperature utilizing green solvents, reagents and assessed as an anti-corrosion catalyst for the commercially important mild steel (MS) alloy subjected to highly aggressive 0.5 M sulphuric acid (H 2 SO 4 ) solution by several electrochemical methods (polarization techniques and Electrochemical impedance spectroscopy) allied with various surface characterization techniques such as attenuated total reflectance (ATR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and atomic force microscopy (AFM). Furthermore, the experimental results were theoretically supplemented by density functional theory (DFT) treatment. AMIB delivered significant corrosion protection even at very low concentrations and at various temperatures. The findings from electrochemical and surface characterization techniques were also supplemented by temperature kinetics study. The adsorption mechanism of AMIB molecules on metal substrate follow Langmuir's adsorption isotherm. The overall corrosion mitigation mechanism assessed from various techniques and methods was found to be comprehensive in nature. The present study may pave the way for combating corrosion with this cost effective and eco-friendly strategy.",
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Comprehensive adsorption characteristics of a newly synthesized and sustainable anti-corrosion catalyst on mild steel surface exposed to a highly corrosive electrolytic solution. / Kumar, Raman; Kim, Hansung; Umapathi, Reddicherla; Yadav, Ompal Singh; Singh, Gurmeet.

In: Journal of Molecular Liquids, Vol. 268, 15.10.2018, p. 37-48.

Research output: Contribution to journalArticle

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AU - Singh, Gurmeet

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AB - A new environmental-friendly imine compound viz. 4-(2-amino-3-methylphenyl)imino)methyl)benzaldehyde (AMIB) was sustainably synthesized at room temperature utilizing green solvents, reagents and assessed as an anti-corrosion catalyst for the commercially important mild steel (MS) alloy subjected to highly aggressive 0.5 M sulphuric acid (H 2 SO 4 ) solution by several electrochemical methods (polarization techniques and Electrochemical impedance spectroscopy) allied with various surface characterization techniques such as attenuated total reflectance (ATR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and atomic force microscopy (AFM). Furthermore, the experimental results were theoretically supplemented by density functional theory (DFT) treatment. AMIB delivered significant corrosion protection even at very low concentrations and at various temperatures. The findings from electrochemical and surface characterization techniques were also supplemented by temperature kinetics study. The adsorption mechanism of AMIB molecules on metal substrate follow Langmuir's adsorption isotherm. The overall corrosion mitigation mechanism assessed from various techniques and methods was found to be comprehensive in nature. The present study may pave the way for combating corrosion with this cost effective and eco-friendly strategy.

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