Conceptual design of three-dimensional CoN/Ni3N-coupled nanograsses integrated on N-doped carbon to serve as efficient and robust water splitting electrocatalysts

Chaiti Ray, Su Chan Lee, Bingjun Jin, Aniruddha Kundu, Jong Hyeok Park, Seong Chan Jun

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Developing binder-free, low-cost, and efficient electrocatalysts for water splitting is very important to meet the ever-increasing global energy demands. We have judiciously designed a polyaniline (PANI)-mediated protocol for the synthesis of nickel-cobalt nitride (NCN) heterostructures on carbon cloth (CC) to be applied as catalysts for full electrochemical splitting of water. Controlled pyrolyzation of the nickel-cobalt precursor on PANI-coated CC generates assembled grass-like nanostructures of cobalt nitride (CoN) and nickel nitride (Ni3N) along with beneficial, conductive nitrogen-doped carbon layers on CC for improved electrochemical activity. The generation of numerous catalytically active centers with expeditious charge and mass transportation due to the incorporated nickel and high mechanical stability owing to the self-supporting nature of the designed material result in excellent and stable electrocatalytic performance. The designed NCN/CC electrode requires low overpotentials (η10) of 247 and 68 mV to attain a current density of 10 mA cm-2 during oxygen evolution and hydrogen evolution reactions, respectively, with appreciable stability (>90% retention of the initial current density) over a 24 h long electrochemical test in 1.0 M KOH. Finally, the NCN/CC electrocatalyst is utilized to demonstrate full alkaline water splitting at a cell voltage of 1.56 V to deliver the current density of 10 mA cm-2 with tremendous stability over 240 h. Moreover, NCN/CC could afford a stable current density of 10 mA cm-2 towards full water splitting at 1.59 V cell voltage in acidic electrolyte with 100 h long-term stability. These results suggest its prospects as a substitute for expensive noble-metal-based water splitting electrocatalysts in practical applications.

Original languageEnglish
Pages (from-to)4466-4476
Number of pages11
JournalJournal of Materials Chemistry A
Volume6
Issue number10
DOIs
Publication statusPublished - 2018 Mar 14

Fingerprint

Electrocatalysts
Conceptual design
Cobalt
Nickel
Nitrides
Carbon
Water
Carbon nitride
Current density
Polyaniline
Mass transportation
Mechanical stability
Electric potential
Precious metals
Electrolytes
Binders
Heterojunctions
Hydrogen
Nanostructures
Nitrogen

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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title = "Conceptual design of three-dimensional CoN/Ni3N-coupled nanograsses integrated on N-doped carbon to serve as efficient and robust water splitting electrocatalysts",
abstract = "Developing binder-free, low-cost, and efficient electrocatalysts for water splitting is very important to meet the ever-increasing global energy demands. We have judiciously designed a polyaniline (PANI)-mediated protocol for the synthesis of nickel-cobalt nitride (NCN) heterostructures on carbon cloth (CC) to be applied as catalysts for full electrochemical splitting of water. Controlled pyrolyzation of the nickel-cobalt precursor on PANI-coated CC generates assembled grass-like nanostructures of cobalt nitride (CoN) and nickel nitride (Ni3N) along with beneficial, conductive nitrogen-doped carbon layers on CC for improved electrochemical activity. The generation of numerous catalytically active centers with expeditious charge and mass transportation due to the incorporated nickel and high mechanical stability owing to the self-supporting nature of the designed material result in excellent and stable electrocatalytic performance. The designed NCN/CC electrode requires low overpotentials (η10) of 247 and 68 mV to attain a current density of 10 mA cm-2 during oxygen evolution and hydrogen evolution reactions, respectively, with appreciable stability (>90{\%} retention of the initial current density) over a 24 h long electrochemical test in 1.0 M KOH. Finally, the NCN/CC electrocatalyst is utilized to demonstrate full alkaline water splitting at a cell voltage of 1.56 V to deliver the current density of 10 mA cm-2 with tremendous stability over 240 h. Moreover, NCN/CC could afford a stable current density of 10 mA cm-2 towards full water splitting at 1.59 V cell voltage in acidic electrolyte with 100 h long-term stability. These results suggest its prospects as a substitute for expensive noble-metal-based water splitting electrocatalysts in practical applications.",
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Conceptual design of three-dimensional CoN/Ni3N-coupled nanograsses integrated on N-doped carbon to serve as efficient and robust water splitting electrocatalysts. / Ray, Chaiti; Lee, Su Chan; Jin, Bingjun; Kundu, Aniruddha; Park, Jong Hyeok; Jun, Seong Chan.

In: Journal of Materials Chemistry A, Vol. 6, No. 10, 14.03.2018, p. 4466-4476.

Research output: Contribution to journalArticle

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AU - Ray, Chaiti

AU - Lee, Su Chan

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AU - Jun, Seong Chan

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N2 - Developing binder-free, low-cost, and efficient electrocatalysts for water splitting is very important to meet the ever-increasing global energy demands. We have judiciously designed a polyaniline (PANI)-mediated protocol for the synthesis of nickel-cobalt nitride (NCN) heterostructures on carbon cloth (CC) to be applied as catalysts for full electrochemical splitting of water. Controlled pyrolyzation of the nickel-cobalt precursor on PANI-coated CC generates assembled grass-like nanostructures of cobalt nitride (CoN) and nickel nitride (Ni3N) along with beneficial, conductive nitrogen-doped carbon layers on CC for improved electrochemical activity. The generation of numerous catalytically active centers with expeditious charge and mass transportation due to the incorporated nickel and high mechanical stability owing to the self-supporting nature of the designed material result in excellent and stable electrocatalytic performance. The designed NCN/CC electrode requires low overpotentials (η10) of 247 and 68 mV to attain a current density of 10 mA cm-2 during oxygen evolution and hydrogen evolution reactions, respectively, with appreciable stability (>90% retention of the initial current density) over a 24 h long electrochemical test in 1.0 M KOH. Finally, the NCN/CC electrocatalyst is utilized to demonstrate full alkaline water splitting at a cell voltage of 1.56 V to deliver the current density of 10 mA cm-2 with tremendous stability over 240 h. Moreover, NCN/CC could afford a stable current density of 10 mA cm-2 towards full water splitting at 1.59 V cell voltage in acidic electrolyte with 100 h long-term stability. These results suggest its prospects as a substitute for expensive noble-metal-based water splitting electrocatalysts in practical applications.

AB - Developing binder-free, low-cost, and efficient electrocatalysts for water splitting is very important to meet the ever-increasing global energy demands. We have judiciously designed a polyaniline (PANI)-mediated protocol for the synthesis of nickel-cobalt nitride (NCN) heterostructures on carbon cloth (CC) to be applied as catalysts for full electrochemical splitting of water. Controlled pyrolyzation of the nickel-cobalt precursor on PANI-coated CC generates assembled grass-like nanostructures of cobalt nitride (CoN) and nickel nitride (Ni3N) along with beneficial, conductive nitrogen-doped carbon layers on CC for improved electrochemical activity. The generation of numerous catalytically active centers with expeditious charge and mass transportation due to the incorporated nickel and high mechanical stability owing to the self-supporting nature of the designed material result in excellent and stable electrocatalytic performance. The designed NCN/CC electrode requires low overpotentials (η10) of 247 and 68 mV to attain a current density of 10 mA cm-2 during oxygen evolution and hydrogen evolution reactions, respectively, with appreciable stability (>90% retention of the initial current density) over a 24 h long electrochemical test in 1.0 M KOH. Finally, the NCN/CC electrocatalyst is utilized to demonstrate full alkaline water splitting at a cell voltage of 1.56 V to deliver the current density of 10 mA cm-2 with tremendous stability over 240 h. Moreover, NCN/CC could afford a stable current density of 10 mA cm-2 towards full water splitting at 1.59 V cell voltage in acidic electrolyte with 100 h long-term stability. These results suggest its prospects as a substitute for expensive noble-metal-based water splitting electrocatalysts in practical applications.

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