Conducting polymer coated non-woven graphite fiber film for dye-sensitized solar cells: Superior Pt- and FTO-free counter electrodes

Hyojung Kim, Ganapathy Veerappan, Jong Hyeok Park

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Conventional platinum (Pt) or emerging materials for the counter electrodes (CEs) of dye-sensitized solar cells (DSSCs) have been fabricated on a fluorine-doped tin oxide (FTO) substrate. In this study, carbon paper with three-dimensional (3D) carbon fiber networks, which is highly porous, but has sufficient space for efficient transportation of electrolytes, is used in replace of the conventional heavy, rigid and expensive FTO/glass substrate in DSSC CEs. To prove the advantages of these highly conductive carbon paper electrodes, a thin poly(3,4-ethylenedioxythiophene) (PEDOT) film is uniformly coated on the surface of 3D carbon paper via a chemical polymerization method. The catalytic properties of the PEDOT/carbon paper as the CE in a DSSC are studied using cyclic voltammetry, J-V, and IPCE measurements. Interestingly, the PEDOT/carbon paper CE exhibits better functionality as a CE for tri-iodide reduction as compared to conventional Pt/FTO-based CEs. The controlled DSSC with a PEDOT/carbon paper CE exhibits a power conversion efficiency of 8.05% under 100 mW·cm-2 illumination, which is higher than that of conventional DSSCs with standard Pt/FTO CEs (7.41%).

Original languageEnglish
Pages (from-to)164-168
Number of pages5
JournalElectrochimica Acta
Volume137
DOIs
Publication statusPublished - 2014 Aug 10

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Graphite fibers
Fluorine
Conducting polymers
Platinum
Tin oxides
Electrodes
Carbon
Dye-sensitized solar cells
stannic oxide
Iodides
Substrates
Electrolytes
Conversion efficiency
Cyclic voltammetry
Carbon fibers
Lighting
Polymerization
Glass
poly(3,4-ethylene dioxythiophene)

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electrochemistry

Cite this

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title = "Conducting polymer coated non-woven graphite fiber film for dye-sensitized solar cells: Superior Pt- and FTO-free counter electrodes",
abstract = "Conventional platinum (Pt) or emerging materials for the counter electrodes (CEs) of dye-sensitized solar cells (DSSCs) have been fabricated on a fluorine-doped tin oxide (FTO) substrate. In this study, carbon paper with three-dimensional (3D) carbon fiber networks, which is highly porous, but has sufficient space for efficient transportation of electrolytes, is used in replace of the conventional heavy, rigid and expensive FTO/glass substrate in DSSC CEs. To prove the advantages of these highly conductive carbon paper electrodes, a thin poly(3,4-ethylenedioxythiophene) (PEDOT) film is uniformly coated on the surface of 3D carbon paper via a chemical polymerization method. The catalytic properties of the PEDOT/carbon paper as the CE in a DSSC are studied using cyclic voltammetry, J-V, and IPCE measurements. Interestingly, the PEDOT/carbon paper CE exhibits better functionality as a CE for tri-iodide reduction as compared to conventional Pt/FTO-based CEs. The controlled DSSC with a PEDOT/carbon paper CE exhibits a power conversion efficiency of 8.05{\%} under 100 mW·cm-2 illumination, which is higher than that of conventional DSSCs with standard Pt/FTO CEs (7.41{\%}).",
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Conducting polymer coated non-woven graphite fiber film for dye-sensitized solar cells : Superior Pt- and FTO-free counter electrodes. / Kim, Hyojung; Veerappan, Ganapathy; Park, Jong Hyeok.

In: Electrochimica Acta, Vol. 137, 10.08.2014, p. 164-168.

Research output: Contribution to journalArticle

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