Constructing ordered paths to improve the charge separation and light harvesting capacity towards efficient solar water oxidation performance

D. Amaranatha Reddy, K. Arun Joshi Reddy, Da Hye Hong, Madhusudana Gopannagari, D. Praveen Kumar, Tae Kyu Kim

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)


Photoelectrochemical (PEC) water-splitting performance can be expressed as the product of efficiencies of light absorption (ηabs), charge separation (ηsep) and charge transfer (ηtrans) processes. In BiVO4 photoanodes, the ηtrans has been greatly enhanced by integrating various low-price oxygen evolution electrocatalysts but improving ηabs×ηsep efficiency remains a great challenge. Considering this challenge, here, we fabricate inverse opal (IO)-SnO2@BiVO4 type-II heterojunction photoanodes and investigate the ηabs×ηsep efficiency by tailoring the amount of BiVO4 on the IO-SnO2 nanostructures. The optimized IO-SnO2@BiVO4 photoanode exhibits ηabs×ηsep of 62.91 % at 1.23 V vs. reversible hydrogen electrode (RHE), which is much higher than that of the bare BiVO4 (16.14 %). The significantly improved ηabs×ηsep is attributed to the introduction of IO-SnO2, which provides a high solar light-harvesting capability by diffuse scattering and coherent multiple internal scattering. Moreover, it greatly improves the intrinsic charge transport and reduces interface contact resistance due to ordered paths for electron migration. Even though ηabs×ηsep is high, the majority of the photogenerated holes are lost at the surface/electrolyte recombination, resulting in a very low ηtrans of 24.93 % at 1.23 V vs. RHE. To improve the ηtrans performance, an oxygen evolution catalyst is deposited on the surface of optimized IO-SnO2@BiVO4, and it greatly increases the ηtrans (96.29 %) and achieves JH2O of 3.57 mA∙cm−2 with excellent stability for 10 h. In addition, we achieve an applied bias photon‐to‐current efficiency of nearly 1.02 % at 0.72 V vs. RHE. Overall, the obtained results and fabrication process are considered a significant step toward achieving sustainability.

Original languageEnglish
Article number118761
JournalApplied Catalysis B: Environmental
Publication statusPublished - 2020 Jul 15

Bibliographical note

Funding Information:
This work was supported by Samsung Science & Technology Foundation fund by Samsung Electronics ( SSTF-BA1702-07 ).

Publisher Copyright:
© 2020 Elsevier B.V.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology


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