Continuous ZIF-8/reduced graphene oxide nanocoating for ultrafast oil/water separation

Dae Woo Kim, Kiwon Eum, Hanim Kim, Daeok Kim, Matheus Dorneles de Mello, Kangho Park, Michael Tsapatsis

Research output: Contribution to journalArticle

13 Citations (Scopus)


Continuous ZIF-8/reduced graphene oxide (RGO)nanocoating is fabricated by growing ZIF-8 on RGO-coated polyurethane (PU)foam. Surface modification of PU foam can be easily achieved by immersing the PU foam in GO solution, followed by mild thermal treatment to turn the GO layer into RGO layer. Adhesion between polymer foam and ZIF-8 layer was enhanced by the inserted RGO layer because oxygen-containing groups of RGO could interact with Zn2+ precursor of ZIF-8 localizing the layer growth preferentially on the surface of RGO. The synergetic hydrophobic/oleophilic properties of RGO and ZIF-8 enable selective oil absorption of PU foam with an absorption capacity of 15–35 g/g depending on the viscosity of organic solvents. Most of all, the ZIF-8/RGO coated PU foam can filter organic solvent selectively via vacuum filtration, showing ultrafast hexane flux up to 800,000 Lm−2 h−1 and no water flux.

Original languageEnglish
Pages (from-to)509-515
Number of pages7
JournalChemical Engineering Journal
Publication statusPublished - 2019 Sep 15

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Fingerprint Dive into the research topics of 'Continuous ZIF-8/reduced graphene oxide nanocoating for ultrafast oil/water separation'. Together they form a unique fingerprint.

  • Cite this