Convenient molecular approach of size and shape controlled ZnSe and ZnTe nanocrystals

Y. W. Jun; J. I. Park; J. Cheon

doi:10.1557/proc-635-c4.47

Convenient molecular approach of size and shape controlled ZnSe and ZnTe nanocrystals

Y. W. Jun, J. I. Park, J. Cheon

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

Our study describes a convenient one-step synthesis of ZnSe and ZnTe nanocrystals (NC) whose sizes and shapes are precisely tuned by varing the growth temperature or stabilizing surfactants. We utilized molecular precursors, bis(phenylselenolate or phenyltellurolato)zinc-N,N,N',N'-tetramethylethylenediamine (TMEDA), which effectively produce 0-dimensional sphere or 1-dimensional nanorods of ZnSe or ZnTe, respectively. Nanocrystals are highly monodispersed and luminescent; the emission wavelength varies over a wide range depending on the particle size. This study constitutes a nice demonstration of direct size and shape controlled synthesis of semiconductor nanocrystals and this method can be extended to the synthesis of nanocrystals of other materials.

Original language	English
Pages (from-to)	C4471-C4476
Journal	Materials Research Society Symposium - Proceedings
Volume	635
DOIs	https://doi.org/10.1557/proc-635-c4.47
Publication status	Published - 2001
Event	Anisotropic Nanoparticles-Synthesis, Characterization and Applications - Boston, MA, United States Duration: 2000 Nov 27 → 2000 Nov 29

Bibliographical note

Funding Information:
This work was supported by the Korea Science and Engineering Foundation (1999-1-122-001-5) and we thank Korea Basic Science Institute for the TEM analyses.

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1557/proc-635-c4.47

Cite this

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abstract = "Our study describes a convenient one-step synthesis of ZnSe and ZnTe nanocrystals (NC) whose sizes and shapes are precisely tuned by varing the growth temperature or stabilizing surfactants. We utilized molecular precursors, bis(phenylselenolate or phenyltellurolato)zinc-N,N,N',N'-tetramethylethylenediamine (TMEDA), which effectively produce 0-dimensional sphere or 1-dimensional nanorods of ZnSe or ZnTe, respectively. Nanocrystals are highly monodispersed and luminescent; the emission wavelength varies over a wide range depending on the particle size. This study constitutes a nice demonstration of direct size and shape controlled synthesis of semiconductor nanocrystals and this method can be extended to the synthesis of nanocrystals of other materials.",

author = "Jun, {Y. W.} and Park, {J. I.} and J. Cheon",

note = "Funding Information: This work was supported by the Korea Science and Engineering Foundation (1999-1-122-001-5) and we thank Korea Basic Science Institute for the TEM analyses.; Anisotropic Nanoparticles-Synthesis, Characterization and Applications ; Conference date: 27-11-2000 Through 29-11-2000",

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AU - Jun, Y. W.

AU - Park, J. I.

AU - Cheon, J.

N1 - Funding Information: This work was supported by the Korea Science and Engineering Foundation (1999-1-122-001-5) and we thank Korea Basic Science Institute for the TEM analyses.

PY - 2001

Y1 - 2001

N2 - Our study describes a convenient one-step synthesis of ZnSe and ZnTe nanocrystals (NC) whose sizes and shapes are precisely tuned by varing the growth temperature or stabilizing surfactants. We utilized molecular precursors, bis(phenylselenolate or phenyltellurolato)zinc-N,N,N',N'-tetramethylethylenediamine (TMEDA), which effectively produce 0-dimensional sphere or 1-dimensional nanorods of ZnSe or ZnTe, respectively. Nanocrystals are highly monodispersed and luminescent; the emission wavelength varies over a wide range depending on the particle size. This study constitutes a nice demonstration of direct size and shape controlled synthesis of semiconductor nanocrystals and this method can be extended to the synthesis of nanocrystals of other materials.

AB - Our study describes a convenient one-step synthesis of ZnSe and ZnTe nanocrystals (NC) whose sizes and shapes are precisely tuned by varing the growth temperature or stabilizing surfactants. We utilized molecular precursors, bis(phenylselenolate or phenyltellurolato)zinc-N,N,N',N'-tetramethylethylenediamine (TMEDA), which effectively produce 0-dimensional sphere or 1-dimensional nanorods of ZnSe or ZnTe, respectively. Nanocrystals are highly monodispersed and luminescent; the emission wavelength varies over a wide range depending on the particle size. This study constitutes a nice demonstration of direct size and shape controlled synthesis of semiconductor nanocrystals and this method can be extended to the synthesis of nanocrystals of other materials.

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VL - 635

SP - C4471-C4476

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

SN - 0272-9172

T2 - Anisotropic Nanoparticles-Synthesis, Characterization and Applications

Y2 - 27 November 2000 through 29 November 2000

ER -

Convenient molecular approach of size and shape controlled ZnSe and ZnTe nanocrystals

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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