Coordination polymer nanobamboos of {FexIn1-x}-MIL- 88B: Induced formation of a virtual in-MIL-88B

Shin Ae Park, Hee Jung Lee, Yea Jin Cho, Sora Choi, Moonhyun Oh

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1-x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1-x}-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In 0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86Å, respectively. These values of {Fe0.06In 0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1-x}-MIL-88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In-MIL-88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.

Original languageEnglish
Pages (from-to)5559-5564
Number of pages6
JournalChemistry - A European Journal
Volume20
Issue number19
DOIs
Publication statusPublished - 2014 May 5

Fingerprint

Metal ions
Polymers
Bamboo
Chemical analysis
Fabrication
Ions
N(1)-methyl-2-lysergic acid diethylamide

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

Cite this

Park, Shin Ae ; Lee, Hee Jung ; Cho, Yea Jin ; Choi, Sora ; Oh, Moonhyun. / Coordination polymer nanobamboos of {FexIn1-x}-MIL- 88B : Induced formation of a virtual in-MIL-88B. In: Chemistry - A European Journal. 2014 ; Vol. 20, No. 19. pp. 5559-5564.
@article{1c54de7688774773aae48a59a0352300,
title = "Coordination polymer nanobamboos of {FexIn1-x}-MIL- 88B: Induced formation of a virtual in-MIL-88B",
abstract = "A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1-x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1-x}-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In 0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86{\AA}, respectively. These values of {Fe0.06In 0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1-x}-MIL-88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In-MIL-88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.",
author = "Park, {Shin Ae} and Lee, {Hee Jung} and Cho, {Yea Jin} and Sora Choi and Moonhyun Oh",
year = "2014",
month = "5",
day = "5",
doi = "10.1002/chem.201304515",
language = "English",
volume = "20",
pages = "5559--5564",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "19",

}

Coordination polymer nanobamboos of {FexIn1-x}-MIL- 88B : Induced formation of a virtual in-MIL-88B. / Park, Shin Ae; Lee, Hee Jung; Cho, Yea Jin; Choi, Sora; Oh, Moonhyun.

In: Chemistry - A European Journal, Vol. 20, No. 19, 05.05.2014, p. 5559-5564.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Coordination polymer nanobamboos of {FexIn1-x}-MIL- 88B

T2 - Induced formation of a virtual in-MIL-88B

AU - Park, Shin Ae

AU - Lee, Hee Jung

AU - Cho, Yea Jin

AU - Choi, Sora

AU - Oh, Moonhyun

PY - 2014/5/5

Y1 - 2014/5/5

N2 - A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1-x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1-x}-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In 0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86Å, respectively. These values of {Fe0.06In 0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1-x}-MIL-88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In-MIL-88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.

AB - A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1-x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1-x}-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In 0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86Å, respectively. These values of {Fe0.06In 0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework. In bamboo: The preparation of nanobamboos of {FexIn1-x}-MIL-88B is demonstrated. The compositions of the nanobamboos are regulated by altering the amount of metal ions used during their preparation. In addition, the formation of a virtual In-MIL-88B, which is difficult to create in a typical reaction, is induced with the assistance of small amounts of Fe3+ ions.

UR - http://www.scopus.com/inward/record.url?scp=84899929579&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84899929579&partnerID=8YFLogxK

U2 - 10.1002/chem.201304515

DO - 10.1002/chem.201304515

M3 - Article

AN - SCOPUS:84899929579

VL - 20

SP - 5559

EP - 5564

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 19

ER -