Copper Hydroxide Nanorods Decorated Porous Graphene Foam Electrodes for Non-enzymatic Glucose Sensing

Iman Shackery; Umakant Patil; Atiye Pezeshki; Nanasaheb M. Shinde; Shinill Kang; Seongil Im; Seong Chan Jun

doi:10.1016/j.electacta.2016.01.047

Copper Hydroxide Nanorods Decorated Porous Graphene Foam Electrodes for Non-enzymatic Glucose Sensing

Iman Shackery, Umakant Patil, Atiye Pezeshki, Nanasaheb M. Shinde, Shinill Kang, Seongil Im, Seong Chan Jun

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

For the first time, we are reporting the flower-like structure of copper hydroxide (Cu(OH)₂) on freestanding 3D porous graphene foam (PGF). The Cu(OH)₂ flowerlike structure fabricated via a simple and cost-effective chemical bath deposition (CBD) method. The CBD is a facile method which provide relatively inexpensive, simple and convenient route for large area deposition. The structural and morphological characterization of Cu(OH)₂ reveals that, Cu(OH)₂ flower-like structure, consists of nanorods (diameter ∼100 nm), are well covered over the porous graphene framework. The flower-like structure of copper hydroxide on PGF provides large surface area (Effective surface area = 9.44 cm²), which leads to enhancement of electrochemical activity. Significantly, Cu(OH)₂/PGF electrode showed the excellent sensitivity (up to 3.36 mA mM^-1 cm^-2), low detection limit (1.2 μM), wide linear range (1.2 μM ∼ 6 mM). The Cu(OH)₂/PGF exhibited good reproducibility and excellent selectivity toward usual interfering materials such as lactose, fructose, Acetaminophen, ascorbic acid, dopamine and urea in 1 M KOH aqueous electrolyte.

Original language	English
Pages (from-to)	954-961
Number of pages	8
Journal	Electrochimica Acta
Volume	191
DOIs	https://doi.org/10.1016/j.electacta.2016.01.047
Publication status	Published - 2016 Feb 10

Bibliographical note

Funding Information:
This work was partially supported by the Priority Research Centers Program (2009-0093823), the Basic Science Research Program (2014-11-0553), Korea Research Fellowship Program funded by the Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea (2015-11-1063), and the Korean Government (MSIP) (No. 2015R1A5A1037668) through the National Research Foundation (NRF) of Korea funded by the Ministry of Education, Science and Technology (MEST).

Publisher Copyright:
© 2016 Elsevier Ltd. All rights reserved.

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)
Electrochemistry

Access to Document

10.1016/j.electacta.2016.01.047

Cite this

@article{96ad243991d34774acb26c321882fed2,

title = "Copper Hydroxide Nanorods Decorated Porous Graphene Foam Electrodes for Non-enzymatic Glucose Sensing",

abstract = "For the first time, we are reporting the flower-like structure of copper hydroxide (Cu(OH)2) on freestanding 3D porous graphene foam (PGF). The Cu(OH)2 flowerlike structure fabricated via a simple and cost-effective chemical bath deposition (CBD) method. The CBD is a facile method which provide relatively inexpensive, simple and convenient route for large area deposition. The structural and morphological characterization of Cu(OH)2 reveals that, Cu(OH)2 flower-like structure, consists of nanorods (diameter ∼100 nm), are well covered over the porous graphene framework. The flower-like structure of copper hydroxide on PGF provides large surface area (Effective surface area = 9.44 cm2), which leads to enhancement of electrochemical activity. Significantly, Cu(OH)2/PGF electrode showed the excellent sensitivity (up to 3.36 mA mM-1 cm-2), low detection limit (1.2 μM), wide linear range (1.2 μM ∼ 6 mM). The Cu(OH)2/PGF exhibited good reproducibility and excellent selectivity toward usual interfering materials such as lactose, fructose, Acetaminophen, ascorbic acid, dopamine and urea in 1 M KOH aqueous electrolyte.",

author = "Iman Shackery and Umakant Patil and Atiye Pezeshki and Shinde, {Nanasaheb M.} and Shinill Kang and Seongil Im and Jun, {Seong Chan}",

note = "Funding Information: This work was partially supported by the Priority Research Centers Program (2009-0093823), the Basic Science Research Program (2014-11-0553), Korea Research Fellowship Program funded by the Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea (2015-11-1063), and the Korean Government (MSIP) (No. 2015R1A5A1037668) through the National Research Foundation (NRF) of Korea funded by the Ministry of Education, Science and Technology (MEST). Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd. All rights reserved.",

year = "2016",

month = feb,

day = "10",

doi = "10.1016/j.electacta.2016.01.047",

language = "English",

volume = "191",

pages = "954--961",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Copper Hydroxide Nanorods Decorated Porous Graphene Foam Electrodes for Non-enzymatic Glucose Sensing

AU - Shackery, Iman

AU - Patil, Umakant

AU - Pezeshki, Atiye

AU - Shinde, Nanasaheb M.

AU - Kang, Shinill

AU - Im, Seongil

AU - Jun, Seong Chan

N1 - Funding Information: This work was partially supported by the Priority Research Centers Program (2009-0093823), the Basic Science Research Program (2014-11-0553), Korea Research Fellowship Program funded by the Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea (2015-11-1063), and the Korean Government (MSIP) (No. 2015R1A5A1037668) through the National Research Foundation (NRF) of Korea funded by the Ministry of Education, Science and Technology (MEST). Publisher Copyright: © 2016 Elsevier Ltd. All rights reserved.

PY - 2016/2/10

Y1 - 2016/2/10

N2 - For the first time, we are reporting the flower-like structure of copper hydroxide (Cu(OH)2) on freestanding 3D porous graphene foam (PGF). The Cu(OH)2 flowerlike structure fabricated via a simple and cost-effective chemical bath deposition (CBD) method. The CBD is a facile method which provide relatively inexpensive, simple and convenient route for large area deposition. The structural and morphological characterization of Cu(OH)2 reveals that, Cu(OH)2 flower-like structure, consists of nanorods (diameter ∼100 nm), are well covered over the porous graphene framework. The flower-like structure of copper hydroxide on PGF provides large surface area (Effective surface area = 9.44 cm2), which leads to enhancement of electrochemical activity. Significantly, Cu(OH)2/PGF electrode showed the excellent sensitivity (up to 3.36 mA mM-1 cm-2), low detection limit (1.2 μM), wide linear range (1.2 μM ∼ 6 mM). The Cu(OH)2/PGF exhibited good reproducibility and excellent selectivity toward usual interfering materials such as lactose, fructose, Acetaminophen, ascorbic acid, dopamine and urea in 1 M KOH aqueous electrolyte.

AB - For the first time, we are reporting the flower-like structure of copper hydroxide (Cu(OH)2) on freestanding 3D porous graphene foam (PGF). The Cu(OH)2 flowerlike structure fabricated via a simple and cost-effective chemical bath deposition (CBD) method. The CBD is a facile method which provide relatively inexpensive, simple and convenient route for large area deposition. The structural and morphological characterization of Cu(OH)2 reveals that, Cu(OH)2 flower-like structure, consists of nanorods (diameter ∼100 nm), are well covered over the porous graphene framework. The flower-like structure of copper hydroxide on PGF provides large surface area (Effective surface area = 9.44 cm2), which leads to enhancement of electrochemical activity. Significantly, Cu(OH)2/PGF electrode showed the excellent sensitivity (up to 3.36 mA mM-1 cm-2), low detection limit (1.2 μM), wide linear range (1.2 μM ∼ 6 mM). The Cu(OH)2/PGF exhibited good reproducibility and excellent selectivity toward usual interfering materials such as lactose, fructose, Acetaminophen, ascorbic acid, dopamine and urea in 1 M KOH aqueous electrolyte.

UR - http://www.scopus.com/inward/record.url?scp=84957030921&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84957030921&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2016.01.047

DO - 10.1016/j.electacta.2016.01.047

M3 - Article

AN - SCOPUS:84957030921

VL - 191

SP - 954

EP - 961

JO - Electrochimica Acta

JF - Electrochimica Acta

SN - 0013-4686

ER -

Copper Hydroxide Nanorods Decorated Porous Graphene Foam Electrodes for Non-enzymatic Glucose Sensing

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this