Core-Shell ZnO@Microporous Organic Polymer Nanospheres as Enhanced Piezo-Triboelectric Energy Harvesting Materials

Chang Wan Kang; Dong Min Lee; Jina Park; Sohee Bang; Sang Woo Kim; Seung Uk Son

doi:10.1002/anie.202209659

Core-Shell ZnO@Microporous Organic Polymer Nanospheres as Enhanced Piezo-Triboelectric Energy Harvesting Materials

Chang Wan Kang, Dong Min Lee, Jina Park, Sohee Bang, Sang Woo Kim, Seung Uk Son

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Core-shell nanospheres were prepared by the homogeneous coating of piezoelectric ZnO nanorod aggregates with triboelectric microporous organic polymer (MOP). The small energy harvesting performance of ZnO@MOP was significantly enhanced, compared with those of ZnO and MOP, due to the piezoelectrification-induced polarization of inner ZnO and the enhanced generation of tribopositive charges of MOP. Piezo-triboelectric nanogenerators (PTENGs) fabricated with ZnO@MOP showed peak-to-peak voltages of up to 534 V and a maximum power density of 1.19 mW cm⁻². In addition, the PTENGs showed excellent durability for 30 000 cycles, demonstrating as efficient power sources for charging electrolytic capacitors and for operating 200 green light emitting diode bulbs.

Original language	English
Article number	e202209659
Journal	Angewandte Chemie - International Edition
Volume	61
Issue number	46
DOIs	https://doi.org/10.1002/anie.202209659
Publication status	Published - 2022 Nov 14

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant (No. 2020R1A2C2004310 and No. 2022R1A3B1078291) funded by the Korea government (MSIT).

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.202209659

Cite this

@article{da2f8f20cd1a469bb02f22ff1f376790,

title = "Core-Shell ZnO@Microporous Organic Polymer Nanospheres as Enhanced Piezo-Triboelectric Energy Harvesting Materials",

abstract = "Core-shell nanospheres were prepared by the homogeneous coating of piezoelectric ZnO nanorod aggregates with triboelectric microporous organic polymer (MOP). The small energy harvesting performance of ZnO@MOP was significantly enhanced, compared with those of ZnO and MOP, due to the piezoelectrification-induced polarization of inner ZnO and the enhanced generation of tribopositive charges of MOP. Piezo-triboelectric nanogenerators (PTENGs) fabricated with ZnO@MOP showed peak-to-peak voltages of up to 534 V and a maximum power density of 1.19 mW cm−2. In addition, the PTENGs showed excellent durability for 30 000 cycles, demonstrating as efficient power sources for charging electrolytic capacitors and for operating 200 green light emitting diode bulbs.",

author = "Kang, {Chang Wan} and Lee, {Dong Min} and Jina Park and Sohee Bang and Kim, {Sang Woo} and Son, {Seung Uk}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant (No. 2020R1A2C2004310 and No. 2022R1A3B1078291) funded by the Korea government (MSIT). Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

month = nov,

day = "14",

doi = "10.1002/anie.202209659",

language = "English",

volume = "61",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "46",

}

TY - JOUR

T1 - Core-Shell ZnO@Microporous Organic Polymer Nanospheres as Enhanced Piezo-Triboelectric Energy Harvesting Materials

AU - Kang, Chang Wan

AU - Lee, Dong Min

AU - Park, Jina

AU - Bang, Sohee

AU - Kim, Sang Woo

AU - Son, Seung Uk

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant (No. 2020R1A2C2004310 and No. 2022R1A3B1078291) funded by the Korea government (MSIT). Publisher Copyright: © 2022 Wiley-VCH GmbH.

PY - 2022/11/14

Y1 - 2022/11/14

N2 - Core-shell nanospheres were prepared by the homogeneous coating of piezoelectric ZnO nanorod aggregates with triboelectric microporous organic polymer (MOP). The small energy harvesting performance of ZnO@MOP was significantly enhanced, compared with those of ZnO and MOP, due to the piezoelectrification-induced polarization of inner ZnO and the enhanced generation of tribopositive charges of MOP. Piezo-triboelectric nanogenerators (PTENGs) fabricated with ZnO@MOP showed peak-to-peak voltages of up to 534 V and a maximum power density of 1.19 mW cm−2. In addition, the PTENGs showed excellent durability for 30 000 cycles, demonstrating as efficient power sources for charging electrolytic capacitors and for operating 200 green light emitting diode bulbs.

AB - Core-shell nanospheres were prepared by the homogeneous coating of piezoelectric ZnO nanorod aggregates with triboelectric microporous organic polymer (MOP). The small energy harvesting performance of ZnO@MOP was significantly enhanced, compared with those of ZnO and MOP, due to the piezoelectrification-induced polarization of inner ZnO and the enhanced generation of tribopositive charges of MOP. Piezo-triboelectric nanogenerators (PTENGs) fabricated with ZnO@MOP showed peak-to-peak voltages of up to 534 V and a maximum power density of 1.19 mW cm−2. In addition, the PTENGs showed excellent durability for 30 000 cycles, demonstrating as efficient power sources for charging electrolytic capacitors and for operating 200 green light emitting diode bulbs.

UR - http://www.scopus.com/inward/record.url?scp=85140013393&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85140013393&partnerID=8YFLogxK

U2 - 10.1002/anie.202209659

DO - 10.1002/anie.202209659

M3 - Article

C2 - 36130197

AN - SCOPUS:85140013393

SN - 1433-7851

VL - 61

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

M1 - e202209659

ER -

Core-Shell ZnO@Microporous Organic Polymer Nanospheres as Enhanced Piezo-Triboelectric Energy Harvesting Materials

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this