Correlations between the surface energy and the tilt angle on the homeotropic polyimide surface

Young Hwan Kim, Ji Hun Lim, Byeong Yun Oh, Byoung Yong Kim, Jeong Min Han, Jeong Yeon Hwang, Dae Shik Seo

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

We investigated the correlations between the surface energy and the tilt angle on homeotropic polyimide (PI) surfaces subjected to rubbing using ion beam (IB) irradiation. The tilt angle of nematic liquid crystal (NLC) decreased with increased rubbing times. Also, the tilt angle of NLC was measured to be homeotropically aligned and then rapidly changed to homogeneous alignment with increasing IB irradiation time. We assumed that the LC alignment depends strongly on the C-O bonds created from CO bonds on the PI surface broken with IB irradiation, which was confirmed through X-ray photoelectron spectroscopy measurements. In addition, the contact angle on the PI surface decreased with increasing IB irradiation time. Therefore, we conclude that the IB irradiation is attributed to the high surface energy and the compositional variation of the homeotropic PI, resulting in a transition of NLC orientation.

Original languageEnglish
Pages (from-to)J134-J137
JournalJournal of the Electrochemical Society
Volume156
Issue number6
DOIs
Publication statusPublished - 2009 May 8

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Interfacial energy
Polyimides
Ion beams
Irradiation
Nematic liquid crystals
Carbon Monoxide
Crystal orientation
Contact angle
X ray photoelectron spectroscopy

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Kim, Young Hwan ; Lim, Ji Hun ; Oh, Byeong Yun ; Kim, Byoung Yong ; Han, Jeong Min ; Hwang, Jeong Yeon ; Seo, Dae Shik. / Correlations between the surface energy and the tilt angle on the homeotropic polyimide surface. In: Journal of the Electrochemical Society. 2009 ; Vol. 156, No. 6. pp. J134-J137.
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abstract = "We investigated the correlations between the surface energy and the tilt angle on homeotropic polyimide (PI) surfaces subjected to rubbing using ion beam (IB) irradiation. The tilt angle of nematic liquid crystal (NLC) decreased with increased rubbing times. Also, the tilt angle of NLC was measured to be homeotropically aligned and then rapidly changed to homogeneous alignment with increasing IB irradiation time. We assumed that the LC alignment depends strongly on the C-O bonds created from CO bonds on the PI surface broken with IB irradiation, which was confirmed through X-ray photoelectron spectroscopy measurements. In addition, the contact angle on the PI surface decreased with increasing IB irradiation time. Therefore, we conclude that the IB irradiation is attributed to the high surface energy and the compositional variation of the homeotropic PI, resulting in a transition of NLC orientation.",
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Correlations between the surface energy and the tilt angle on the homeotropic polyimide surface. / Kim, Young Hwan; Lim, Ji Hun; Oh, Byeong Yun; Kim, Byoung Yong; Han, Jeong Min; Hwang, Jeong Yeon; Seo, Dae Shik.

In: Journal of the Electrochemical Society, Vol. 156, No. 6, 08.05.2009, p. J134-J137.

Research output: Contribution to journalArticle

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T1 - Correlations between the surface energy and the tilt angle on the homeotropic polyimide surface

AU - Kim, Young Hwan

AU - Lim, Ji Hun

AU - Oh, Byeong Yun

AU - Kim, Byoung Yong

AU - Han, Jeong Min

AU - Hwang, Jeong Yeon

AU - Seo, Dae Shik

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AB - We investigated the correlations between the surface energy and the tilt angle on homeotropic polyimide (PI) surfaces subjected to rubbing using ion beam (IB) irradiation. The tilt angle of nematic liquid crystal (NLC) decreased with increased rubbing times. Also, the tilt angle of NLC was measured to be homeotropically aligned and then rapidly changed to homogeneous alignment with increasing IB irradiation time. We assumed that the LC alignment depends strongly on the C-O bonds created from CO bonds on the PI surface broken with IB irradiation, which was confirmed through X-ray photoelectron spectroscopy measurements. In addition, the contact angle on the PI surface decreased with increasing IB irradiation time. Therefore, we conclude that the IB irradiation is attributed to the high surface energy and the compositional variation of the homeotropic PI, resulting in a transition of NLC orientation.

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