CO2 bubble assisted layer-by-layer self-assembly of graphene oxide multilayer film

Jiwoong Heo, Hyejoong Jeong, Jinkee Hong

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Graphene oxide (GO) multilayer films have been studied for various applications. The method of layer-by-layer (LbL) self-assembly is widely used for the preparation of multilayer films since it provides precise control of the nanoscopic features of the film. However, controlling nanoscopic features of GO film via conventional LbL self-assembly faces several challenges because of inherent aggregation behaviors of GO sheets in aqueous suspension. Herein, we report a novel method of CO2 bubble assisted LbL self-assembly of GO films. The adsorption kinetics of colloidal GO suspension was controlled via CO2 bubbles during LbL self-assembly. We characterized the effect of CO2 bubbles on the LbL assembly of GO sheets by analyzing the nanoscopic features of the multilayered GO films. The thickness, mass, surface morphology, and internal structure were analyzed by a profilometer, quartz crystal microbalance, scanning electron microscopy, atomic force microscopy, and photoluminescence spectroscopy.

Original languageEnglish
Pages (from-to)76-80
Number of pages5
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume533
DOIs
Publication statusPublished - 2017 Nov 20

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Graphite
Multilayer films
Self assembly
Graphene
Oxide films
self assembly
graphene
bubbles
oxides
Oxides
oxide films
Suspensions
Photoluminescence spectroscopy
Quartz crystal microbalances
Surface morphology
profilometers
Atomic force microscopy
Agglomeration
quartz crystals
microbalances

All Science Journal Classification (ASJC) codes

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

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title = "CO2 bubble assisted layer-by-layer self-assembly of graphene oxide multilayer film",
abstract = "Graphene oxide (GO) multilayer films have been studied for various applications. The method of layer-by-layer (LbL) self-assembly is widely used for the preparation of multilayer films since it provides precise control of the nanoscopic features of the film. However, controlling nanoscopic features of GO film via conventional LbL self-assembly faces several challenges because of inherent aggregation behaviors of GO sheets in aqueous suspension. Herein, we report a novel method of CO2 bubble assisted LbL self-assembly of GO films. The adsorption kinetics of colloidal GO suspension was controlled via CO2 bubbles during LbL self-assembly. We characterized the effect of CO2 bubbles on the LbL assembly of GO sheets by analyzing the nanoscopic features of the multilayered GO films. The thickness, mass, surface morphology, and internal structure were analyzed by a profilometer, quartz crystal microbalance, scanning electron microscopy, atomic force microscopy, and photoluminescence spectroscopy.",
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CO2 bubble assisted layer-by-layer self-assembly of graphene oxide multilayer film. / Heo, Jiwoong; Jeong, Hyejoong; Hong, Jinkee.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 533, 20.11.2017, p. 76-80.

Research output: Contribution to journalArticle

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N2 - Graphene oxide (GO) multilayer films have been studied for various applications. The method of layer-by-layer (LbL) self-assembly is widely used for the preparation of multilayer films since it provides precise control of the nanoscopic features of the film. However, controlling nanoscopic features of GO film via conventional LbL self-assembly faces several challenges because of inherent aggregation behaviors of GO sheets in aqueous suspension. Herein, we report a novel method of CO2 bubble assisted LbL self-assembly of GO films. The adsorption kinetics of colloidal GO suspension was controlled via CO2 bubbles during LbL self-assembly. We characterized the effect of CO2 bubbles on the LbL assembly of GO sheets by analyzing the nanoscopic features of the multilayered GO films. The thickness, mass, surface morphology, and internal structure were analyzed by a profilometer, quartz crystal microbalance, scanning electron microscopy, atomic force microscopy, and photoluminescence spectroscopy.

AB - Graphene oxide (GO) multilayer films have been studied for various applications. The method of layer-by-layer (LbL) self-assembly is widely used for the preparation of multilayer films since it provides precise control of the nanoscopic features of the film. However, controlling nanoscopic features of GO film via conventional LbL self-assembly faces several challenges because of inherent aggregation behaviors of GO sheets in aqueous suspension. Herein, we report a novel method of CO2 bubble assisted LbL self-assembly of GO films. The adsorption kinetics of colloidal GO suspension was controlled via CO2 bubbles during LbL self-assembly. We characterized the effect of CO2 bubbles on the LbL assembly of GO sheets by analyzing the nanoscopic features of the multilayered GO films. The thickness, mass, surface morphology, and internal structure were analyzed by a profilometer, quartz crystal microbalance, scanning electron microscopy, atomic force microscopy, and photoluminescence spectroscopy.

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