The spectra of far-infrared transmission in Tb3 Fe5 O12 magnetoelectric single crystals have been studied in the range between 15 and 100 cm-1, in magnetic fields up to 10 T, and for temperatures between 5 and 150 K. We attribute some of the observed infrared-active excitations to electric dipole transitions between ligand-field split states of Tb3+ ions. Anticrossing between the magnetic exchange excitation and the ligand-field transition occurs at the temperature between 60 and 80 K. The corresponding coupling energy for this interaction is 6cm -1. Temperature-induced softening of the hybrid IR excitation correlates with the increase in the static dielectric constant. We discuss the possibility for hybrid excitations of magnons and ligand-field states and their possible connection to the magnetoelectric effect in Tb3 Fe 5 O12.
|Journal||Physical Review B - Condensed Matter and Materials Physics|
|Publication status||Published - 2010 Jul 15|
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics