Covalent Functionalization of Exfoliated Arsenic with Chlorocarbene

Jiri Sturala, Adriano Ambrosi, Zdeněk Sofer, Martin Pumera

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Few-layer and monolayer arsenic (arsenene) materials have been attracting great attention mainly from a theoretical perspective. Chemical modification of these materials would expand significantly the range of their applications. Here, we describe a chlorocarbene-mediated modification of exfoliated layered arsenic materials. Carbene-based species are highly reactive and offer further possibilities of functionalization. Our approach for modifying the arsenic surface by chlorocarbene generated from organolithium and dichloromethane resulted in a large surface coverage and a highly luminescent functionalized material, opening the door for its application in modern optoelectronic devices.

Original languageEnglish
Pages (from-to)14837-14840
Number of pages4
JournalAngewandte Chemie - International Edition
Volume57
Issue number45
DOIs
Publication statusPublished - 2018 Nov 5

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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