Critical Role of the Chemical Environment of Interlayer Na Sites: An Effective Way to Improve the Na Ion Electrode Activity of Layered Titanate

Meina Piao, Seung Mi Oh, Joohyun Lim, Sun Ha Kim, Sung Chul Kim, Yun Kyung Jo, Oc Hee Han, Seong Ju Hwang

Research output: Contribution to journalArticle

Abstract

The chemical environments of the interlayer Na sites of layered titanate are finely controlled by the intercalation of n-alkylamine with various alkyl chain lengths to explore an effective way to improve its electrode functionality for sodium-ion batteries (SIBs). The n-alkylamine intercalation via ion-exchange and exfoliation-restacking routes allows the modification of in-plane structures of layered titanate to be tuned. Among the present n-alkylamine-intercalates, the n-pentylamine-intercalated titanate shows the largest discharge capacity with the best rate characteristics, underscoring the critical role of optimized intracrystalline structure in improving the SIB electrode performance of layered titanate. The creation of turbostratic in-plane structure degrades the SIB electrode performance of layered titanate, indicating the detrimental effect of in-plane structural disorder on electrode activity. 23Na magic-angle spinning nuclear magnetic resonance spectroscopy demonstrates that the n-alkylamine-intercalated titanates possess two different interlayer Na+ sites near ammonium head groups/titanate layers and near alkyl chains. The intercalation of long-chain molecules increases the population of the latter site and the overall mobility of Na+ ions, which is responsible for the improvement of electrode activity upon n-alkylamine intercalation. The present study highlights that the increased population of interlayer metal sites remote from the host layers is effective in improving the electrode functionality of layered metal oxide for SIBs and multivalent ion batteries.

Original languageEnglish
Pages (from-to)33112-33123
Number of pages12
JournalACS Applied Materials and Interfaces
Volume10
Issue number39
DOIs
Publication statusPublished - 2018 Oct 3

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Ions
Intercalation
Electrodes
Sodium
Metals
Magic angle spinning
Chain length
Ammonium Compounds
Nuclear magnetic resonance spectroscopy
Ion exchange
Molecules
Oxides

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Piao, Meina ; Oh, Seung Mi ; Lim, Joohyun ; Kim, Sun Ha ; Kim, Sung Chul ; Jo, Yun Kyung ; Han, Oc Hee ; Hwang, Seong Ju. / Critical Role of the Chemical Environment of Interlayer Na Sites : An Effective Way to Improve the Na Ion Electrode Activity of Layered Titanate. In: ACS Applied Materials and Interfaces. 2018 ; Vol. 10, No. 39. pp. 33112-33123.
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Critical Role of the Chemical Environment of Interlayer Na Sites : An Effective Way to Improve the Na Ion Electrode Activity of Layered Titanate. / Piao, Meina; Oh, Seung Mi; Lim, Joohyun; Kim, Sun Ha; Kim, Sung Chul; Jo, Yun Kyung; Han, Oc Hee; Hwang, Seong Ju.

In: ACS Applied Materials and Interfaces, Vol. 10, No. 39, 03.10.2018, p. 33112-33123.

Research output: Contribution to journalArticle

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AU - Piao, Meina

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AU - Kim, Sung Chul

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AU - Han, Oc Hee

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