Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler

Won Bae Lim, Viswanathan S. Saji, Yong Soo Cho, Yong Gun Shul, Sangwoo Lim, Jae Hyuk Jang, Hong Ryul Lee

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt%. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li2O substitution occurred. It was observed that the substitution of 2 wt% Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.

Original languageEnglish
Pages (from-to)3849-3853
Number of pages5
JournalJournal of Non-Crystalline Solids
Volume354
Issue number32
DOIs
Publication statusPublished - 2008 Aug 15

Fingerprint

Crystallization
fillers
Dielectric properties
Fillers
dielectric properties
crystallization
Substitution reactions
substitutes
densification
Densification
Temperature
Zinc
calcium
Calcium
sintering
Sintering
zinc
ceramics
Crystalline materials
Glass

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

Lim, Won Bae ; Saji, Viswanathan S. ; Cho, Yong Soo ; Shul, Yong Gun ; Lim, Sangwoo ; Jang, Jae Hyuk ; Lee, Hong Ryul. / Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler. In: Journal of Non-Crystalline Solids. 2008 ; Vol. 354, No. 32. pp. 3849-3853.
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abstract = "Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt{\%}. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt{\%} Li2O substitution occurred. It was observed that the substitution of 2 wt{\%} Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.",
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Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler. / Lim, Won Bae; Saji, Viswanathan S.; Cho, Yong Soo; Shul, Yong Gun; Lim, Sangwoo; Jang, Jae Hyuk; Lee, Hong Ryul.

In: Journal of Non-Crystalline Solids, Vol. 354, No. 32, 15.08.2008, p. 3849-3853.

Research output: Contribution to journalArticle

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AU - Lim, Won Bae

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AU - Cho, Yong Soo

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AB - Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt%. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li2O substitution occurred. It was observed that the substitution of 2 wt% Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.

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