Decomposition of aqueous chlorinated contaminants by UV irradiation with H2O2

Eunsung Kan, Chang Il Koh, Kyunghyuk Lee, Joonwun Kang

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

In the present study, the decomposition rates of carbon tetrachloride (CCl4) and 2,4-dichlorophenol (2,4-DCP) in water by the ultraviolet (UV) light irradiation alone and H2O2/UV were experimentally investigated. The detailed experimental studies have been conducted for examining treatment capacities of the two different ultraviolet light sources (low and medium pressure Hg arc) in H2O2/UV processes. The low or medium UV lamp alone resulted in a 60%–90% decomposition of 2,4-DCP while a slight addition of H2O2 resulted in a drastic enhancement of the 2,4-DCP decomposition rate. The decomposition rate of 2,4-DCP with the medium pressure UV lamp alone was about 3–6 times greater than the low pressure UV lamp alone. In the direct photolysis of aqueous CCl4, the medium pressure UV lamp had advantage over the low pressure UV lamp because the molar extinction coefficient of CCl4 at shorter wavelength (210–220 nm) is about 20 to 50 times higher than that at 254 nm. However, adding H2O2 to the medium pressure UV lamp system rendered a negative oxidation rate because H2O2 acted as a UV absorber being competitive with CCl4 due to negligible reaction between CCl4 and OH radicals. The results from the present study indicated significant influence of the photochemical properties of the target contaminants on the photochemical treatment characteristics for designing cost-effective UV-based degradation of toxic contaminants.

Original languageEnglish
Pages (from-to)429-435
Number of pages7
JournalFrontiers of Environmental Science and Engineering
Volume9
Issue number3
DOIs
Publication statusPublished - 2015 Jun 1

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irradiation
decomposition
pollutant
low pressure
extinction coefficient
photolysis
lamp
experimental study
wavelength
oxidation
degradation
rate
carbon
cost
water

All Science Journal Classification (ASJC) codes

  • Environmental Science(all)

Cite this

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abstract = "In the present study, the decomposition rates of carbon tetrachloride (CCl4) and 2,4-dichlorophenol (2,4-DCP) in water by the ultraviolet (UV) light irradiation alone and H2O2/UV were experimentally investigated. The detailed experimental studies have been conducted for examining treatment capacities of the two different ultraviolet light sources (low and medium pressure Hg arc) in H2O2/UV processes. The low or medium UV lamp alone resulted in a 60{\%}–90{\%} decomposition of 2,4-DCP while a slight addition of H2O2 resulted in a drastic enhancement of the 2,4-DCP decomposition rate. The decomposition rate of 2,4-DCP with the medium pressure UV lamp alone was about 3–6 times greater than the low pressure UV lamp alone. In the direct photolysis of aqueous CCl4, the medium pressure UV lamp had advantage over the low pressure UV lamp because the molar extinction coefficient of CCl4 at shorter wavelength (210–220 nm) is about 20 to 50 times higher than that at 254 nm. However, adding H2O2 to the medium pressure UV lamp system rendered a negative oxidation rate because H2O2 acted as a UV absorber being competitive with CCl4 due to negligible reaction between CCl4 and OH radicals. The results from the present study indicated significant influence of the photochemical properties of the target contaminants on the photochemical treatment characteristics for designing cost-effective UV-based degradation of toxic contaminants.",
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Decomposition of aqueous chlorinated contaminants by UV irradiation with H2O2 . / Kan, Eunsung; Koh, Chang Il; Lee, Kyunghyuk; Kang, Joonwun.

In: Frontiers of Environmental Science and Engineering, Vol. 9, No. 3, 01.06.2015, p. 429-435.

Research output: Contribution to journalArticle

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