Deprotonation induced formation of möbius aromatic [32]heptaphyrins

Won Young Cha, Tomoki Yoneda, Sangsu Lee, Jong Min Lim, Atsuhiro Osuka, Dongho Kim

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Upon treatment with tetrabutylammonium fluoride (TBAF), [32]heptaphyrins 1 and 2 underwent conformational changes to form Möbius aromatic species, as indicated by the appearance of sharp and intense B-like bands and distinct Q-like bands, long-lived S1-states, and relatively large TPA cross-section values. Hence, deprotonation has been shown to be an additional effective means to induce the formation of Möbius aromatic expanded porphyrins.

Original languageEnglish
Pages (from-to)548-550
Number of pages3
JournalChemical Communications
Volume50
Issue number5
DOIs
Publication statusPublished - 2014 Dec 10

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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