Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF

Ying Hu, Mahnseok Kye, Ji Young Jung, Yong beom Lim, Juyoung Yoon

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A new triarylborane compound 1 is described as fluorescent probe for HF gas with high sensitivity and selectivity. The system utilized the coordination of a fluoride ion to the boron center in 1 to cause perturbation in the energy transfer pathway and the π conjugation, which induced distinct fluorescent quenching. A probe 1-coated film was further applied to detect HF gas via a unique capacitance change.

Original languageEnglish
Pages (from-to)2621-2627
Number of pages7
JournalSensors and Actuators, B: Chemical
Volume255
DOIs
Publication statusPublished - 2018 Feb

Bibliographical note

Funding Information:
This study was financially supported by a grant from the National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP No. 2012R1A3A2048814). This research was also supported by NRF of Korea (MSIP No. 2017R1A2A2A05069773), Civil-Military Technology Cooperation Program, and Yonsei University Future-leading Research Initiative. Mass spectral data were obtained from the Korea Basic Science Institute (Daegu) using a Jeol JMS 700 high-resolution mass spectrometer. MHz solid state NMR spectrometer (unityINOVA, Agilent Technologies, U.S.A) at KBSI Western Seoul center. 19 F NMR and 11 B NMR data were acquired on 500

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

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