Design of exceptionally strong and conductive Cu alloys beyond the conventional speculation via the interfacial energy-controlled dispersion of γ-Al2O3 nanoparticles

Seung Zeon Han, Kwang Ho Kim, Joonhee Kang, Hongrae Joh, Sang Min Kim, Jee Hyuk Ahn, Jehyun Lee, Sung Hwan Lim, Byungchan Han

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The development of Cu-based alloys with high-mechanical properties (strength, ductility) and electrical conductivity plays a key role over a wide range of industrial applications. Successful design of the materials, however, has been rare due to the improvement of mutually exclusive properties as conventionally speculated. In this paper, we demonstrate that these contradictory material properties can be improved simultaneously if the interfacial energies of heterogeneous interfaces are carefully controlled. We uniformly disperse γ-Al2O3 nanoparticles over Cu matrix, and then we controlled atomic level morphology of the interface γ-Al2O3 //Cu by adding Ti solutes. It is shown that the Ti dramatically drives the interfacial phase transformation from very irregular to homogeneous spherical morphologies resulting in substantial enhancement of the mechanical property of Cu matrix. Furthermore, the Ti removes impurities (O and Al) in the Cu matrix by forming oxides leading to recovery of the electrical conductivity of pure Cu. We validate experimental results using TEM and EDX combined with first-principles density functional theory (DFT) calculations, which all consistently poise that our materials are suitable for industrial applications.

Original languageEnglish
Article number17364
JournalScientific reports
Volume5
DOIs
Publication statusPublished - 2015 Nov 30

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interfacial energy
nanoparticles
matrices
mechanical properties
electrical resistivity
ductility
phase transformations
solutes
recovery
density functional theory
impurities
transmission electron microscopy
oxides
augmentation

All Science Journal Classification (ASJC) codes

  • General

Cite this

Zeon Han, Seung ; Kim, Kwang Ho ; Kang, Joonhee ; Joh, Hongrae ; Kim, Sang Min ; Ahn, Jee Hyuk ; Lee, Jehyun ; Lim, Sung Hwan ; Han, Byungchan. / Design of exceptionally strong and conductive Cu alloys beyond the conventional speculation via the interfacial energy-controlled dispersion of γ-Al2O3 nanoparticles. In: Scientific reports. 2015 ; Vol. 5.
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Design of exceptionally strong and conductive Cu alloys beyond the conventional speculation via the interfacial energy-controlled dispersion of γ-Al2O3 nanoparticles. / Zeon Han, Seung; Kim, Kwang Ho; Kang, Joonhee; Joh, Hongrae; Kim, Sang Min; Ahn, Jee Hyuk; Lee, Jehyun; Lim, Sung Hwan; Han, Byungchan.

In: Scientific reports, Vol. 5, 17364, 30.11.2015.

Research output: Contribution to journalArticle

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