Dianion of pyrrole-2-N-(o-hydroxyphenyl)carbaldimine as an interesting tridentate (ONN) ligand system in hypercoordinate silicon complexes

Daniela Gerlach, Erica Brendler, Thomas Heine, Jörg Wagler

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37 Citations (Scopus)

Abstract

The tridentate title ligand was found to act as an (NeqN axOeq) = (Namide,Nimine,O phenolate) ligand as well as an (NaxNeqO ax) ligand in pentacoordinate silicon complexes depending on the substituents at the Si atom. Its two notably different coordination modes in (NeqNaxOeq)Si(CH2)3 and (NaXNeqOax)SiPhMe were studied with X-ray structure analysis as well as 29Si CP/MAS NMR spectroscopy together with quantum chemical calculations of geometry and NMR chemical shielding tensors.

Original languageEnglish
Pages (from-to)234-240
Number of pages7
JournalOrganometallics
Volume26
Issue number1
DOIs
Publication statusPublished - 2007 Jan 1

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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