Diphenylphosphine oxide: An alternative to organotin hydrides in the radical deoxygenation of alcohols

Doo Ok Jang, Dae Hyan Cho, Joonggon Kim

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.

Original languageEnglish
Pages (from-to)3559-3565
Number of pages7
JournalSynthetic Communications
Volume28
Issue number19
Publication statusPublished - 1998 Jan 1

Fingerprint

Hydrides
Boiling liquids
Alcohols
Xylenes
triphenylphosphine oxide
1,4-dioxane

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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abstract = "Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.",
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Diphenylphosphine oxide : An alternative to organotin hydrides in the radical deoxygenation of alcohols. / Jang, Doo Ok; Cho, Dae Hyan; Kim, Joonggon.

In: Synthetic Communications, Vol. 28, No. 19, 01.01.1998, p. 3559-3565.

Research output: Contribution to journalArticle

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