Direct synthesis of graphene quantum dots from multilayer graphene flakes through grinding assisted co-solvent ultrasonication for all-printed resistive switching arrays

Junaid Ali, Ghayas Ud Din Siddiqui, Young Jin Yang, Kang Taek Lee, Kiju Um, Kyung Hyun Choi

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Graphene quantum dots (GQD) with diameters as small as ∼2 nm were synthesized by an efficient chemo-mechanical technique. This involved mortar grinding and ultra-sonication as a means of mechanical energy transfer, while N-methyl-pyrrolidone and 1,2-dichlorobenzene were used for exfoliation and breakdown of graphene nanoplatelets. High resolution transmission electron microscopy images showed that the solution-based GQDs were about 2-4 nm in size, and had a crystalline lattice parameter of 0.24 nm. The technique proved useful for extracting GQDs of the desired size. XRD, Raman and FTIR spectroscopy were used to analyze the quality of the graphene structure within the GQDs. The UV responsive GQDs had a band-gap of 2.6 eV and stronger photoluminescence at 350 nm compared to lower wavelengths of laser excitation. An all-printed 2 × 2 array of memristors based on a GQD embedded polymer matrix fabricated on a flexible PET substrate showed an OFF/ON ratio of just over 7 when read at 100 mV, stable retention despite a high compliance current for ∼100 switching cycles, and a robustness of 200 bending cycles up to 1.5 cm bending diameter without compromise on resistive switching states.

Original languageEnglish
Pages (from-to)5068-5078
Number of pages11
JournalRSC Advances
Volume6
Issue number6
DOIs
Publication statusPublished - 2016 Jan 1

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Graphite
Graphene
Semiconductor quantum dots
Multilayers
Memristors
Laser excitation
Sonication
High resolution transmission electron microscopy
Mortar
Polymer matrix
Energy transfer
Lattice constants
Photoluminescence
Energy gap
Spectroscopy
Crystalline materials
Wavelength
Substrates

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Ali, Junaid ; Siddiqui, Ghayas Ud Din ; Yang, Young Jin ; Lee, Kang Taek ; Um, Kiju ; Choi, Kyung Hyun. / Direct synthesis of graphene quantum dots from multilayer graphene flakes through grinding assisted co-solvent ultrasonication for all-printed resistive switching arrays. In: RSC Advances. 2016 ; Vol. 6, No. 6. pp. 5068-5078.
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Direct synthesis of graphene quantum dots from multilayer graphene flakes through grinding assisted co-solvent ultrasonication for all-printed resistive switching arrays. / Ali, Junaid; Siddiqui, Ghayas Ud Din; Yang, Young Jin; Lee, Kang Taek; Um, Kiju; Choi, Kyung Hyun.

In: RSC Advances, Vol. 6, No. 6, 01.01.2016, p. 5068-5078.

Research output: Contribution to journalArticle

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