Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

Jianxin Song, Naoki Aratani, Ji Haeng Heo, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

Original languageEnglish
Pages (from-to)11868-11869
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number34
DOIs
Publication statusPublished - 2010 Sep 1

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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