Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

Jianxin Song, Naoki Aratani, Ji Haeng Heo, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

Original languageEnglish
Pages (from-to)11868-11869
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number34
DOIs
Publication statusPublished - 2010 Sep 1

Fingerprint

Porphyrins
Dimers
Nitrogen
Chemical activation
Atoms

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Song, Jianxin ; Aratani, Naoki ; Heo, Ji Haeng ; Kim, Dongho ; Shinokubo, Hiroshi ; Osuka, Atsuhiro. / Directly Pd(II)-bridged porphyrin belts with remarkable curvatures. In: Journal of the American Chemical Society. 2010 ; Vol. 132, No. 34. pp. 11868-11869.
@article{6d49c0fcba8a4053aeed122dc319fc0a,
title = "Directly Pd(II)-bridged porphyrin belts with remarkable curvatures",
abstract = "A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.",
author = "Jianxin Song and Naoki Aratani and Heo, {Ji Haeng} and Dongho Kim and Hiroshi Shinokubo and Atsuhiro Osuka",
year = "2010",
month = "9",
day = "1",
doi = "10.1021/ja1046654",
language = "English",
volume = "132",
pages = "11868--11869",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "34",

}

Song, J, Aratani, N, Heo, JH, Kim, D, Shinokubo, H & Osuka, A 2010, 'Directly Pd(II)-bridged porphyrin belts with remarkable curvatures', Journal of the American Chemical Society, vol. 132, no. 34, pp. 11868-11869. https://doi.org/10.1021/ja1046654

Directly Pd(II)-bridged porphyrin belts with remarkable curvatures. / Song, Jianxin; Aratani, Naoki; Heo, Ji Haeng; Kim, Dongho; Shinokubo, Hiroshi; Osuka, Atsuhiro.

In: Journal of the American Chemical Society, Vol. 132, No. 34, 01.09.2010, p. 11868-11869.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

AU - Song, Jianxin

AU - Aratani, Naoki

AU - Heo, Ji Haeng

AU - Kim, Dongho

AU - Shinokubo, Hiroshi

AU - Osuka, Atsuhiro

PY - 2010/9/1

Y1 - 2010/9/1

N2 - A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

AB - A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

UR - http://www.scopus.com/inward/record.url?scp=77956080109&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77956080109&partnerID=8YFLogxK

U2 - 10.1021/ja1046654

DO - 10.1021/ja1046654

M3 - Article

C2 - 20698526

AN - SCOPUS:77956080109

VL - 132

SP - 11868

EP - 11869

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 34

ER -