Dye-sensitized solar cells employing amphiphilic poly(ethylene glycol) electrolytes

Rajkumar Patel, Jin Ah Seo, Joo Hwan Koh, Jong Hak Kim, Yong Soo Kang

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Poly(ethylene glycol) (PEG) was modified with a long alkyl acid to produce a self-organized amphiphilic polymer (amPEG). FT-IR and NMR spectroscopies confirmed the amPEG synthesis. This polymer was complexed with lithium iodide (LiI) and 1-methyl-3-propylimidazolium iodide (MPII) to prepare polymer electrolytes to be applied to dye-sensitized solar cells (DSSC). FT-IR studies showed that upon the addition of litium salt the free ether and ester carbonyl bands shifted towards lower wavenumbers, indicating the complexation of Li ions with oxygens on the amPEG. Alkylation and salt introduction reduced PEG crystallinity, as characterized by wide angle X-ray scattering (WAXS) and differential scanning calorimetry (DSC). The ionic conductivities of the polymer electrolytes increased with increasing salt concentrations, and the energy conversion efficiency of DSSC reached 2.6% at 100 mW cm-2 for amPEG/MPII system which is higher than amPEG/LiI. This may be due to the higher mobility of MPII ion than the lithium ion in the polymer electrolyte. The interfacial properties between electrolytes and electrodes were investigated using field-emission scanning electron microscopy (FE-SEM) and electrochemical impedance spectroscopy (EIS).

Original languageEnglish
Pages (from-to)169-176
Number of pages8
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume217
Issue number1
DOIs
Publication statusPublished - 2011 Jan 1

Fingerprint

Iodides
iodides
Electrolytes
Polyethylene glycols
glycols
Polymers
ethylene
solar cells
dyes
electrolytes
Lithium
polymers
Salts
lithium
Ions
salts
ions
energy conversion efficiency
alkylation
Alkylation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Physics and Astronomy(all)

Cite this

Patel, Rajkumar ; Seo, Jin Ah ; Koh, Joo Hwan ; Kim, Jong Hak ; Kang, Yong Soo. / Dye-sensitized solar cells employing amphiphilic poly(ethylene glycol) electrolytes. In: Journal of Photochemistry and Photobiology A: Chemistry. 2011 ; Vol. 217, No. 1. pp. 169-176.
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abstract = "Poly(ethylene glycol) (PEG) was modified with a long alkyl acid to produce a self-organized amphiphilic polymer (amPEG). FT-IR and NMR spectroscopies confirmed the amPEG synthesis. This polymer was complexed with lithium iodide (LiI) and 1-methyl-3-propylimidazolium iodide (MPII) to prepare polymer electrolytes to be applied to dye-sensitized solar cells (DSSC). FT-IR studies showed that upon the addition of litium salt the free ether and ester carbonyl bands shifted towards lower wavenumbers, indicating the complexation of Li ions with oxygens on the amPEG. Alkylation and salt introduction reduced PEG crystallinity, as characterized by wide angle X-ray scattering (WAXS) and differential scanning calorimetry (DSC). The ionic conductivities of the polymer electrolytes increased with increasing salt concentrations, and the energy conversion efficiency of DSSC reached 2.6{\%} at 100 mW cm-2 for amPEG/MPII system which is higher than amPEG/LiI. This may be due to the higher mobility of MPII ion than the lithium ion in the polymer electrolyte. The interfacial properties between electrolytes and electrodes were investigated using field-emission scanning electron microscopy (FE-SEM) and electrochemical impedance spectroscopy (EIS).",
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Dye-sensitized solar cells employing amphiphilic poly(ethylene glycol) electrolytes. / Patel, Rajkumar; Seo, Jin Ah; Koh, Joo Hwan; Kim, Jong Hak; Kang, Yong Soo.

In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 217, No. 1, 01.01.2011, p. 169-176.

Research output: Contribution to journalArticle

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