Effect of chemical oxidation of carbon nanofibers (CNFs) on the electrochemical carbon corrosion in polymer electrolyte membrane (PEM) fuel cells is examined. With increasing time of chemical oxidation treatment using an acidic solution, more oxygen functional groups are formed on the surface of CNF resulting in an increasingly hydrophilic carbon surface. This effect contributes to improvements in Pt loading and the distribution of Pt particles on carbon supports. However, the chemical oxidation treatment is found to accelerate electrochemical carbon corrosion. The oxygen functional group and the hydrophilic nature of CNFs after chemical oxidation treatment are believed to encourage the formation of CO2, which is a product of carbon corrosion. From the observed results, it can be concluded that the chemical oxidation of CNFs is beneficial for catalyst loading and distribution. On the other hand, however, it reduces the durability of the PEM fuel cells caused by the electrochemical carbon corrosion.
Bibliographical noteFunding Information:
This work is supported by New & Renewable Energy R&D program (2009T100100606) under the Ministry of Knowledge Economy of Korea, and the National Research Foundation (NRF-2009-009292) of Korea Grant funded by the Korean Government (MEST).
All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Condensed Matter Physics
- Energy Engineering and Power Technology