Effect of differentiated textural properties of tin oxide aerogels on anode performance in lithium-ion batteries

Yoon Kwang Lee, D. B. Mahadik, Taehee Kim, Wooje Han, Hyung Hee Cho, Hyung Ho Park

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Tin oxide aerogels with different textural structures were obtained using epoxide-initiated gelation of a tin precursor and two different gel drying methods, i.e., ambient pressure drying (APD) and supercritical extraction (SCE) processes. The pore diameters of the tin oxide aerogels synthesized by the APD and SCE methods were 11.3 and 25.3 nm, respectively. Tin oxide aerogels with smaller pore sizes and larger specific surface areas as well as slightly smaller pore volumes and porosities were obtained by the APD process. Different retention properties were observed for the anode materials prepared by APD and SCE, (71.8% and 10.9% after 80 cycles, respectively). This study revealed a relationship between the pore structure of the metal oxide anode material and its cyclability in Li-ion batteries, with metal oxide aerogels with small pore sizes and large specific surface areas showing greatly improved cycling stability in Li-ion battery applications owing to enhanced stability of the pore structure.

Original languageEnglish
Pages (from-to)511-517
Number of pages7
JournalJournal of Alloys and Compounds
Volume732
DOIs
Publication statusPublished - 2018 Jan 25

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Aerogels
Tin oxides
Drying
Anodes
Pore structure
Specific surface area
Oxides
Pore size
Metals
Tin
Epoxy Compounds
Gelation
Gels
Porosity
Lithium-ion batteries
stannic oxide

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "Effect of differentiated textural properties of tin oxide aerogels on anode performance in lithium-ion batteries",
abstract = "Tin oxide aerogels with different textural structures were obtained using epoxide-initiated gelation of a tin precursor and two different gel drying methods, i.e., ambient pressure drying (APD) and supercritical extraction (SCE) processes. The pore diameters of the tin oxide aerogels synthesized by the APD and SCE methods were 11.3 and 25.3 nm, respectively. Tin oxide aerogels with smaller pore sizes and larger specific surface areas as well as slightly smaller pore volumes and porosities were obtained by the APD process. Different retention properties were observed for the anode materials prepared by APD and SCE, (71.8{\%} and 10.9{\%} after 80 cycles, respectively). This study revealed a relationship between the pore structure of the metal oxide anode material and its cyclability in Li-ion batteries, with metal oxide aerogels with small pore sizes and large specific surface areas showing greatly improved cycling stability in Li-ion battery applications owing to enhanced stability of the pore structure.",
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Effect of differentiated textural properties of tin oxide aerogels on anode performance in lithium-ion batteries. / Lee, Yoon Kwang; Mahadik, D. B.; Kim, Taehee; Han, Wooje; Cho, Hyung Hee; Park, Hyung Ho.

In: Journal of Alloys and Compounds, Vol. 732, 25.01.2018, p. 511-517.

Research output: Contribution to journalArticle

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AU - Lee, Yoon Kwang

AU - Mahadik, D. B.

AU - Kim, Taehee

AU - Han, Wooje

AU - Cho, Hyung Hee

AU - Park, Hyung Ho

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AB - Tin oxide aerogels with different textural structures were obtained using epoxide-initiated gelation of a tin precursor and two different gel drying methods, i.e., ambient pressure drying (APD) and supercritical extraction (SCE) processes. The pore diameters of the tin oxide aerogels synthesized by the APD and SCE methods were 11.3 and 25.3 nm, respectively. Tin oxide aerogels with smaller pore sizes and larger specific surface areas as well as slightly smaller pore volumes and porosities were obtained by the APD process. Different retention properties were observed for the anode materials prepared by APD and SCE, (71.8% and 10.9% after 80 cycles, respectively). This study revealed a relationship between the pore structure of the metal oxide anode material and its cyclability in Li-ion batteries, with metal oxide aerogels with small pore sizes and large specific surface areas showing greatly improved cycling stability in Li-ion battery applications owing to enhanced stability of the pore structure.

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