Effect of Fe infiltration to Ni/YSZ solid-oxide-cell fuel electrode on steam/CO2 co-electrolysis

Hyeon Ye Jeong, Si Won Kim, Yonggyun Bae, Kyung Joong Yoon, Jong Ho Lee, Jongsup Hong

Research output: Contribution to journalArticle

Abstract

This study proposes a novel methodology for controlling syngas production from high-temperature CO2/steam co-electrolysis. The co-electrolysis of CO2/steam mixtures is one of the most promising methods to reduce CO2 emissions and mitigate climate change. CO2 and steam are reduced to produce synthetic gas (H2 and CO) through thermo-electrochemical reactions occurring in a solid-oxide-cell fuel electrode. To make this technology viable, it is essential to improve electrochemical cell performance and obtain controllability of gas conversion and product gas selectivity. In this study, Fe infiltration to the Ni/YSZ fuel electrode and subsequent in situ alloying of Ni-Fe is used to enhance the cell performance and syngas productivity. Impregnation of Fe-oxide nanoparticles on the fuel electrode support of solid oxide cells and subsequent in situ alloying Ni-Fe is obtained. Their homogeneous morphology and distribution are obtained by using an advanced infiltration technique. Results show that the Ni-Fe/YSZ fuel electrode enhances CO selectivity and lowers an overvoltage imposed on the cell. This may result in syngas production with higher carbon contents and a higher co-electrolysis system efficiency. In addition, its long-term durability for 500-hour operation is also evidenced with stable syngas production and negligible cell degradation.

Original languageEnglish
Pages (from-to)4949-4958
Number of pages10
JournalInternational Journal of Energy Research
Volume43
Issue number9
DOIs
Publication statusPublished - 2019 Jul

Fingerprint

Solid oxide fuel cells (SOFC)
Electrolysis
Infiltration
Steam
Electrodes
Alloying
Gases
Oxides
Electrochemical cells
Controllability
Impregnation
Climate change
Durability
Productivity
Nanoparticles
Degradation
Carbon
Temperature

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

Jeong, Hyeon Ye ; Kim, Si Won ; Bae, Yonggyun ; Yoon, Kyung Joong ; Lee, Jong Ho ; Hong, Jongsup. / Effect of Fe infiltration to Ni/YSZ solid-oxide-cell fuel electrode on steam/CO2 co-electrolysis. In: International Journal of Energy Research. 2019 ; Vol. 43, No. 9. pp. 4949-4958.
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Effect of Fe infiltration to Ni/YSZ solid-oxide-cell fuel electrode on steam/CO2 co-electrolysis. / Jeong, Hyeon Ye; Kim, Si Won; Bae, Yonggyun; Yoon, Kyung Joong; Lee, Jong Ho; Hong, Jongsup.

In: International Journal of Energy Research, Vol. 43, No. 9, 07.2019, p. 4949-4958.

Research output: Contribution to journalArticle

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AU - Lee, Jong Ho

AU - Hong, Jongsup

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