We have investigated effect of filler particle morphology on the thermal properties of polyimide (PI) nanocomposite films. Gold nanoparticles with various morphologies (non-aggregated, aggregated, and nanorod) were selected as model fillers. To prevent nanoparticle agglomeration in a solvent (1-methyl-2-pyrrolidinone), the surfaces of the gold nanoparticles were modified with triphenylphosphine-3,3',3”-trisulfonic acid trisodium salt (TPPTS), creating the surface sulfonic acid groups. Experiments showed that the thermal diffusivity of the films increased with a large aspect ratio (i.e., nanorod) or aggregation. The addition of gold nanoparticles could reduce the coefficient of thermal expansion (CTE) of PI films in all cases, and the CTE was lowest when the particle size was smallest (i.e., non-aggregated nanoparticles). By considering the effects of the thermal conductivity of the nanocomposite and the interfacial area between the nanoparticles and polymer matrix, we found that increasing the interfacial area between the nanoparticles and polymer matrix by controlling the nanoparticle morphology could reduce the CTE of the nanocomposite more effectively than increasing the thermal diffusivity of the nanocomposite.
|Journal||Colloids and Surfaces A: Physicochemical and Engineering Aspects|
|Publication status||Published - 2019 Oct 20|
Bibliographical noteFunding Information:
This work was supported by a National Research Foundation of Korea (NRF) (grant nos. NRF-2018R1A5A1024127 and 2017R1A2B4007534 ) funded by the Korean government .
All Science Journal Classification (ASJC) codes
- Surfaces and Interfaces
- Physical and Theoretical Chemistry
- Colloid and Surface Chemistry