Effect of interfacial chain structure on toughening behaviour in rubber modified poly(methyl methacrylate)

Hyun Jae Ha, Young Jun Park, Jeong Ho An, Jung-Hyun Kim

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Core-shell composite particles were prepared by a heterocoagulation and annealing process, in which control of the number of chemical linkages in the interfacial zone without changing other properties was possible using five kinds of small size shell particles (SP) with different carboxyl charge density and one large size core particle (LP) with an epoxy functional group. These functional groups were capable of associating with one another through chemical reaction by thermal treatment. With increase of surface functionality of SP, the toughness was found to be higher. This indicated that a higher number of interfacial linkages between core and shell materials resulted in an increase in the critical stress intensity factor KIc of the modified poly(methyl methacrylate) (PMMA) composite. The interfacial properties between core and shell phase therefore play an important role in the impact behaviour of composite materials.

Original languageEnglish
Pages (from-to)490-496
Number of pages7
JournalPolymer International
Volume44
Issue number4
Publication statusPublished - 1997 Dec 1

Fingerprint

Toughening
Rubber
Polymethyl Methacrylate
Polymethyl methacrylates
Functional groups
Composite materials
Charge density
Stress intensity factors
Toughness
Chemical reactions
Heat treatment
Annealing

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

@article{960abbd182844cfc9991761e046b583d,
title = "Effect of interfacial chain structure on toughening behaviour in rubber modified poly(methyl methacrylate)",
abstract = "Core-shell composite particles were prepared by a heterocoagulation and annealing process, in which control of the number of chemical linkages in the interfacial zone without changing other properties was possible using five kinds of small size shell particles (SP) with different carboxyl charge density and one large size core particle (LP) with an epoxy functional group. These functional groups were capable of associating with one another through chemical reaction by thermal treatment. With increase of surface functionality of SP, the toughness was found to be higher. This indicated that a higher number of interfacial linkages between core and shell materials resulted in an increase in the critical stress intensity factor KIc of the modified poly(methyl methacrylate) (PMMA) composite. The interfacial properties between core and shell phase therefore play an important role in the impact behaviour of composite materials.",
author = "Ha, {Hyun Jae} and Park, {Young Jun} and An, {Jeong Ho} and Jung-Hyun Kim",
year = "1997",
month = "12",
day = "1",
language = "English",
volume = "44",
pages = "490--496",
journal = "Polymer International",
issn = "0959-8103",
publisher = "John Wiley and Sons Ltd",
number = "4",

}

Effect of interfacial chain structure on toughening behaviour in rubber modified poly(methyl methacrylate). / Ha, Hyun Jae; Park, Young Jun; An, Jeong Ho; Kim, Jung-Hyun.

In: Polymer International, Vol. 44, No. 4, 01.12.1997, p. 490-496.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Effect of interfacial chain structure on toughening behaviour in rubber modified poly(methyl methacrylate)

AU - Ha, Hyun Jae

AU - Park, Young Jun

AU - An, Jeong Ho

AU - Kim, Jung-Hyun

PY - 1997/12/1

Y1 - 1997/12/1

N2 - Core-shell composite particles were prepared by a heterocoagulation and annealing process, in which control of the number of chemical linkages in the interfacial zone without changing other properties was possible using five kinds of small size shell particles (SP) with different carboxyl charge density and one large size core particle (LP) with an epoxy functional group. These functional groups were capable of associating with one another through chemical reaction by thermal treatment. With increase of surface functionality of SP, the toughness was found to be higher. This indicated that a higher number of interfacial linkages between core and shell materials resulted in an increase in the critical stress intensity factor KIc of the modified poly(methyl methacrylate) (PMMA) composite. The interfacial properties between core and shell phase therefore play an important role in the impact behaviour of composite materials.

AB - Core-shell composite particles were prepared by a heterocoagulation and annealing process, in which control of the number of chemical linkages in the interfacial zone without changing other properties was possible using five kinds of small size shell particles (SP) with different carboxyl charge density and one large size core particle (LP) with an epoxy functional group. These functional groups were capable of associating with one another through chemical reaction by thermal treatment. With increase of surface functionality of SP, the toughness was found to be higher. This indicated that a higher number of interfacial linkages between core and shell materials resulted in an increase in the critical stress intensity factor KIc of the modified poly(methyl methacrylate) (PMMA) composite. The interfacial properties between core and shell phase therefore play an important role in the impact behaviour of composite materials.

UR - http://www.scopus.com/inward/record.url?scp=0031339049&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031339049&partnerID=8YFLogxK

M3 - Article

VL - 44

SP - 490

EP - 496

JO - Polymer International

JF - Polymer International

SN - 0959-8103

IS - 4

ER -